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• W2007014306 abstract "Using 1H and 13C NMR together with density functional theoretical (DFT) calculations, it is shown that p-tert-butylcalix[4]arene-tetrakis(N,N-dimethylthioacetamide) (1) forms a stable equimolecular complex with proton in the form of hydroxonium ion in nitrobenzene-d 5. Protons were offered by hydrogen bis(1,2-dicarbollyl) cobaltate (HDCC) and converted to hydroxonium ions by traces of water. The complex 1·H3O+ adopts a slightly asymmetric but rapidly motionally averaged conformation, which is distinctly more cone-like than ligand 1. The hydroxonium ion H3O+ is bound partly to thiocarbonyl sulphur atoms and partly to phenoxy oxygen atoms of 1 by strong hydrogen bonds and other electrostatic interactions." @default.
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• W2007014306 date "2007-09-01" @default.
• W2007014306 modified "2023-10-16" @default.
• W2007014306 title "A Proton Complex of <i>p</i>-<i>tert</i>-Butylcalix[4]arene-tetrakis(N,N-dimethylthioacetamide): NMR Evidence and Probable Structure" @default.
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• W2007014306 doi "https://doi.org/10.1080/10610270601089360" @default.
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