Matches in SemOpenAlex for { <https://semopenalex.org/work/W2007030230> ?p ?o ?g. }
Showing items 1 to 70 of
70
with 100 items per page.
- W2007030230 endingPage "403" @default.
- W2007030230 startingPage "395" @default.
- W2007030230 abstract "Reactions of 5-methylphenanthridinium iodide ( I ) with oxygen, nitrogen, and carbon nucleophiles, respectively, were studied. 5-Methylphenanthridinium iodide ( I ) yielded in the basic aqueous medium 5-methyl-6-phenanthridone ( II ) and 5,6-dihydro-5-methylphenanthridine ( III ). By NMR spectroscopy in the D 2 O-CD 3 CN solution 5,6-dihydro-6-deuteroxy-5-methylphenanthridine ( IVb ) (pseudobase) was observed as an immediate unstable product. 5-Methylphenanthridinium iodide ( I ) gave the corresponding adducts with methoxide and ethoxide anions, morpholine, piperidine, pyrrolidine, cyanide anion and acetone. Their structure was determined by IR, 1 H and 13 C NMR spectroscopy. Reactions of 5,6-dihydro-5-methyl-6-morpholinophenanthridine ( VII ) were followed by NMR spectroscopy. Morpholino adduct VII gave in the CD 3 CN-D 2 O solution pseudobase ( IVb ) and its products of disproportionation: oxophenanthridine II and dihydrophenanthridine III . Treatment of 5,6-dihydro-5-methyl-6-morpholinophenanthridine ( VII ) with H 2 O/D 2 O in (CH 3 ) 2 CO/(CD 3 ) 2 CO led to CH 3 COCH 2 -/CD 3 COCD 2 - adduct XIa/XIb formation, respectively." @default.
- W2007030230 created "2016-06-24" @default.
- W2007030230 creator A5009582568 @default.
- W2007030230 creator A5035288212 @default.
- W2007030230 creator A5060882664 @default.
- W2007030230 date "1993-01-01" @default.
- W2007030230 modified "2023-09-23" @default.
- W2007030230 title "Reactions of 5-Methylphenanthridinium Iodide with Nucleophiles and Reaction Products Conversion" @default.
- W2007030230 doi "https://doi.org/10.1135/cccc19930395" @default.
- W2007030230 hasPublicationYear "1993" @default.
- W2007030230 type Work @default.
- W2007030230 sameAs 2007030230 @default.
- W2007030230 citedByCount "12" @default.
- W2007030230 crossrefType "journal-article" @default.
- W2007030230 hasAuthorship W2007030230A5009582568 @default.
- W2007030230 hasAuthorship W2007030230A5035288212 @default.
- W2007030230 hasAuthorship W2007030230A5060882664 @default.
- W2007030230 hasConcept C108204754 @default.
- W2007030230 hasConcept C155647269 @default.
- W2007030230 hasConcept C161790260 @default.
- W2007030230 hasConcept C178790620 @default.
- W2007030230 hasConcept C178907741 @default.
- W2007030230 hasConcept C185592680 @default.
- W2007030230 hasConcept C2778870691 @default.
- W2007030230 hasConcept C2779195922 @default.
- W2007030230 hasConcept C2780073701 @default.
- W2007030230 hasConcept C2781056017 @default.
- W2007030230 hasConcept C66974803 @default.
- W2007030230 hasConceptScore W2007030230C108204754 @default.
- W2007030230 hasConceptScore W2007030230C155647269 @default.
- W2007030230 hasConceptScore W2007030230C161790260 @default.
- W2007030230 hasConceptScore W2007030230C178790620 @default.
- W2007030230 hasConceptScore W2007030230C178907741 @default.
- W2007030230 hasConceptScore W2007030230C185592680 @default.
- W2007030230 hasConceptScore W2007030230C2778870691 @default.
- W2007030230 hasConceptScore W2007030230C2779195922 @default.
- W2007030230 hasConceptScore W2007030230C2780073701 @default.
- W2007030230 hasConceptScore W2007030230C2781056017 @default.
- W2007030230 hasConceptScore W2007030230C66974803 @default.
- W2007030230 hasIssue "2" @default.
- W2007030230 hasLocation W20070302301 @default.
- W2007030230 hasOpenAccess W2007030230 @default.
- W2007030230 hasPrimaryLocation W20070302301 @default.
- W2007030230 hasRelatedWork W1503933779 @default.
- W2007030230 hasRelatedWork W1980939198 @default.
- W2007030230 hasRelatedWork W1994881375 @default.
- W2007030230 hasRelatedWork W2007636145 @default.
- W2007030230 hasRelatedWork W2019822848 @default.
- W2007030230 hasRelatedWork W2037263895 @default.
- W2007030230 hasRelatedWork W2054387584 @default.
- W2007030230 hasRelatedWork W2084107671 @default.
- W2007030230 hasRelatedWork W2093964048 @default.
- W2007030230 hasRelatedWork W2332209371 @default.
- W2007030230 hasRelatedWork W2949088748 @default.
- W2007030230 hasRelatedWork W2949722355 @default.
- W2007030230 hasRelatedWork W2949771843 @default.
- W2007030230 hasRelatedWork W2949870584 @default.
- W2007030230 hasRelatedWork W2950118567 @default.
- W2007030230 hasRelatedWork W2950429092 @default.
- W2007030230 hasRelatedWork W2951113292 @default.
- W2007030230 hasRelatedWork W2951180357 @default.
- W2007030230 hasRelatedWork W2952284446 @default.
- W2007030230 hasRelatedWork W2468639859 @default.
- W2007030230 hasVolume "58" @default.
- W2007030230 isParatext "false" @default.
- W2007030230 isRetracted "false" @default.
- W2007030230 magId "2007030230" @default.
- W2007030230 workType "article" @default.