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• W2007050529 abstract "Abstract An innovative gelator was synthesised by non-covalent interactions from triarylamine derivative as N, N, N′, N′-tetrakis(p-octadecylureido-phenyl)-p-phenylenediamine (TOUPPD), and its gelation potential was examined in different organic solvents. The resulting thermo-reversible gel was characterised by using the dropping ball method and a number of other methods. The melting temperature of the gel increased with the TOUPPD concentration. Temperature-dependent UV–vis and fluorescence analysis revealed that the gel exhibited blue fluorescence and H-aggregation in decalin. Intermolecular hydrogen bonding in the TOUPPD gel was observed from FT-IR spectrometry. The morphological self-assembled feature of the gel was studied by atomic force microscopy (AFM). In conductivity and solid electrolyte experiments, the organogel electrolytes exhibited high conductivity (σ) comparable to the corresponding NaClO4/THF solution. The conductivity of the gel electrolytes increased with the concentration of the electrolyte salt. The TOUPPD film exhibited well-defined conductivity of 2.5 × 10–4 to 3.5 × 10− 6 S cm− 1 in the solid state upon addition of a known concentration of trifluoroacetic acid (TFA). Keywords: triarylamineself-assembledaggregationsupramolecular chemistry" @default.
• W2007050529 created "2016-06-24" @default.
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• W2007050529 date "2009-09-22" @default.
• W2007050529 modified "2023-10-09" @default.
• W2007050529 title "Gelation of a highly fluorescent urea-containing triarylamine derivative: <i>N</i>, <i>N</i>, <i>N</i> ′, <i>N</i> ′-tetrakis (<i>p</i>-octadecylureido-phenyl)-<i>p</i>-phenylenediamine in organic solvents" @default.
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• W2007050529 doi "https://doi.org/10.1080/10610270802406603" @default.
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