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- W2007054172 abstract "Es wird über die Reaktion von 19 verschiedenen Halomethylphosphoniumsalzen, [R3PCYnX3–n]X (R = Ph, n-Bu, Me2N, Et2N; Y = H, F; X = Cl, Br, I; n = 0–2), mit Ph3P, n-Bu3P und (R2N)3P berichtet. Als Reaktionsprodukte werden Bisphosphoniumsalze, [R3PCYnX2–nPR′3]X2, und Phosphoranylphosphoniumsalze, [R3P=CYPR′3]X, oder reduzierte (Halo)methylphosphoniumsalze, [R3PCHYnX2–n]X, erhalten. [Ph3PCBrF2]Br und [Bu3PCBrF2]Br reagieren mit R′3P unter Umalkylierung zu [R′3PCBrF2]Br. Die den Reaktionsverlauf beeinflussenden Faktoren werden diskutiert. On the Reaction of Halomethylphosphonium Halides, [R3PCYnX3–n]X, with Phosphanes, R′3P The results of the reaction of 19 different halomethylphosphonium halides, [R3PCYnX3–n]X (R = Ph, n-Bu, Me2N, Et2N; Y = H, F; X = Cl, Br, I; n = 0–2), with Ph3P, n-Bu3P, and (R2N)3P are presented. As reaction products bisphosphonium salts, [R3PCYnX2–nPR′3]X2, and phosphoranylphosphonium salts, [R3P=CYPR′3]X, or reduced (halo)methyl-phosphonium salts, [R3PCHYnX2–n]X, are obtained. [Ph3PCBrF2]Br and [Bu3PCBrF2]Br react with R′3P by trans-alkylation forming [R′3PCBrF2]Br. The factors influencing the course of the reaction are discussed." @default.
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- W2007054172 title "Zur Reaktion von Halomethylphosphoniumhalogeniden, [R3PCYnX3-n]X, mit Phosphanen, R?3P" @default.
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