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• W2007058219 endingPage "13451" @default.
• W2007058219 startingPage "13441" @default.
• W2007058219 abstract "(E,E,E)-1,6-Diaryl(Ar)-1,3,5-hexatrienes (2, Ar = 4-fluorophenyl; 3, Ar = 2,4-difluorophenyl; 4, Ar = 2,4,6-trifluorophenyl; 5, Ar = perfluorophenyl) and (E,E,E)-1-perfluorophenyl-6-phenyl-1,3,5-hexatriene (6) were prepared. The absorption and fluorescence spectra in methylcyclohexane solution showed only a small dependence on the fluorine ring substituent, and were similar to those of the unsubstituted parent compound (1, Ar = phenyl). The solid-state absorption and fluorescence spectra shifted to red relative to those in solution and strongly depended on the substituent. The emission from crystals 1-5 originated mainly from monomeric species with the maximum wavelength (lambda f(max)) of 440-465 nm, which overlapped the emission from molecular aggregates (1-4) or excimeric species (5) in the red region. Crystal 6 exhibited red-shifted (lambda f(max) = 530 nm) and structureless emission due to excimers. The cocrystal of 1 and 5 (1/5) showed red-shifted (lambda f(max) = 558 nm) and distinctly structured emission, not from exciplexes but from the excited states of molecular aggregates in which molecules 1 and 5 strongly interact already in the ground state. These assignments were confirmed by the results of fluorescence lifetime and quantum yield measurements in the solid state. Single-crystal X-ray structure analyses showed that the molecules were basically planar in each crystal, whereas the crystal packing was strongly substituent-dependent. Weak pi-pi interactions in the herringbone (1 and 2) and in the pi-stacked but largely offset structures (3 and 4) account for their predominantly monomeric origin of emission. The observation of excimer fluorescence from 5 was rather unexpected, since the molecules in this crystal were arranged in an offset stacking fashion due to perfluorophenyl-perfluorophenyl (C6F5...C6F5) interaction. The structures of 6 and 1/5 considerably resembled each other, in which molecules were pi-stacked with more face-to-face geometries than those in 5, as a result of strongly attractive perfluorophenyl-phenyl (C6F5...C6H5) interaction. Nevertheless, the fluorescence origin was clearly different for 6 and 1/5. This can be ascribed to the difference in the strength of orbital-orbital interaction between molecular pi-planes in the ground and excited states in crystals." @default.
• W2007058219 created "2016-06-24" @default.
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• W2007058219 creator A5032757204 @default.
• W2007058219 creator A5073923189 @default.
• W2007058219 creator A5089398247 @default.
• W2007058219 date "2007-12-01" @default.
• W2007058219 modified "2023-09-25" @default.
• W2007058219 title "Fluorinated Diphenylpolyenes: Crystal Structures and Emission Properties" @default.
• W2007058219 cites W1657433554 @default.
• W2007058219 cites W1964046622 @default.
• W2007058219 cites W1965526896 @default.
• W2007058219 cites W1968630675 @default.
• W2007058219 cites W1975282532 @default.
• W2007058219 cites W1984521855 @default.
• W2007058219 cites W1984635750 @default.
• W2007058219 cites W1986224063 @default.
• W2007058219 cites W1986476601 @default.
• W2007058219 cites W1986828843 @default.
• W2007058219 cites W1987290467 @default.
• W2007058219 cites W1994850568 @default.
• W2007058219 cites W1994893935 @default.
• W2007058219 cites W1998125139 @default.
• W2007058219 cites W2006947798 @default.
• W2007058219 cites W2008747699 @default.
• W2007058219 cites W2011527021 @default.
• W2007058219 cites W2011685755 @default.
• W2007058219 cites W2013359407 @default.
• W2007058219 cites W2021978165 @default.
• W2007058219 cites W2023271753 @default.
• W2007058219 cites W2025718011 @default.
• W2007058219 cites W2028876885 @default.
• W2007058219 cites W2028911043 @default.
• W2007058219 cites W2030189484 @default.
• W2007058219 cites W2034504806 @default.
• W2007058219 cites W2039008275 @default.
• W2007058219 cites W2040910501 @default.
• W2007058219 cites W2043664855 @default.
• W2007058219 cites W2044650509 @default.
• W2007058219 cites W2049465090 @default.
• W2007058219 cites W2050127753 @default.
• W2007058219 cites W2052350806 @default.
• W2007058219 cites W2055913747 @default.
• W2007058219 cites W2061739467 @default.
• W2007058219 cites W2063663126 @default.
• W2007058219 cites W2064325362 @default.
• W2007058219 cites W2066897219 @default.
• W2007058219 cites W2076374358 @default.
• W2007058219 cites W2081190302 @default.
• W2007058219 cites W2081689243 @default.
• W2007058219 cites W2082425547 @default.
• W2007058219 cites W2083697059 @default.
• W2007058219 cites W2085643400 @default.
• W2007058219 cites W2087702245 @default.
• W2007058219 cites W2091720348 @default.
• W2007058219 cites W2092942621 @default.
• W2007058219 cites W2093825006 @default.
• W2007058219 cites W2094702046 @default.
• W2007058219 cites W2110856715 @default.
• W2007058219 cites W2111091421 @default.
• W2007058219 cites W2113957585 @default.
• W2007058219 cites W2125529623 @default.
• W2007058219 cites W2130564245 @default.
• W2007058219 cites W2130735154 @default.
• W2007058219 cites W2131488016 @default.
• W2007058219 cites W2138333499 @default.
• W2007058219 cites W2139509478 @default.
• W2007058219 cites W2143981217 @default.
• W2007058219 cites W2144304088 @default.
• W2007058219 cites W2149765511 @default.
• W2007058219 cites W2155744992 @default.
• W2007058219 cites W2156929405 @default.
• W2007058219 cites W2157799320 @default.
• W2007058219 cites W2167371974 @default.
• W2007058219 cites W2171559455 @default.
• W2007058219 cites W2172763554 @default.
• W2007058219 cites W2332105895 @default.
• W2007058219 cites W2574328790 @default.
• W2007058219 cites W4240631065 @default.
• W2007058219 doi "https://doi.org/10.1021/jp0766104" @default.
• W2007058219 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18052354" @default.
• W2007058219 hasPublicationYear "2007" @default.
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