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- W2007059638 abstract "The reaction of Cp2Ti(PMe3)2 with C2H2 gives the substitution product Cp2Ti(C2H2)(PMe3), the titanacyclopentadiene Cp2Ti(C4H4), and trans-polyacetylene. A mechanism for the catalytic formation of polyacetylene is proposed. Substituted acetylens R1C2R2 (R1 ≠ R2 = H, Me, Ph) react with Cp2Ti(PMe3)2 in an analogous manner except that no polyalkynes are produced. The Zr derivative Cp2Zr(PMe3)2 and C2H2 yield the labile Cp2Zr(C2H2) (PMe3)." @default.
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- W2007059638 date "1980-07-01" @default.
- W2007059638 modified "2023-10-17" @default.
- W2007059638 title "Reactions of Cp2M(PMe3)2 complexes (M = Ti, Zr) with acetylenes. Selective formation of trans-polyacetylene at low temperatures" @default.
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- W2007059638 doi "https://doi.org/10.1016/s0022-328x(00)98895-8" @default.
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