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- W2007065103 abstract "The lifetimes of the hydrogen bonds formed between resorufin and the solvents ethanol, ethylene glycol, and 1,3-butanediol are measured as a function of temperature. The results show that the hydrogen-bond breaking reaction is strongly influenced by the dynamics of the solvent, in violation of traditional transition-state theory. The relevant solvent dynamics are not well described by the viscosity of the solvent, but do correlate with the dielectric relaxation time. We propose a model in which the hydrogen bond initially breaks to form a poorly solvated, ‘‘dangling’’ hydrogen bond, which has a high probability of geminate recombination. The product is not stabilized until the solvent hydrogen-bond structure can reorganize to incorporate the ‘‘dangling’’ bond. The same reorganization determines the dielectric relaxation time." @default.
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- W2007065103 date "1996-05-15" @default.
- W2007065103 modified "2023-10-05" @default.
- W2007065103 title "The influence of solvent dynamics on the lifetime of solute–solvent hydrogen bonds" @default.
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- W2007065103 doi "https://doi.org/10.1063/1.471454" @default.
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