FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2007069160> ?p ?o ?g. }

• W2007069160 endingPage "117" @default.
• W2007069160 startingPage "103" @default.
• W2007069160 abstract "In an effort to establish a methodology for construction of active sites of artificial enzymes, site-directed attachment of 2,6-diacetylpyridineketoxime (III) to poly(ethylenimine) (PEI) containing β-cyclodextrin (CD) was attempted. The site-directed functionalization exploited at-butylphenyl ester (I) of a carboxylic acid containing a precursor ofIII.Anchoring of thet-butylphenyl group ofIby the CD portion followed by transfer ofIIImoiety to an amino group located in the vicinity of the CD moiety would lead to introduction ofIIIin proximity to the CD moiety. By acylation in DMSO of CD-PEI with the phenyl ester (II), instead of thet-butylphenyl ester,IIIwas introduced randomly to CD-PEI. In the presence of the Ni(II) or Zn(II) complex of theIII-containing CD-PEI prepared by either the site-directed or the random functionalization method, ester hydrolysis of 4-(4′-acetoxy-phenylazo)-benzenesulfonate (IV) was considerably enhanced. Analysis of the kinetic data measured at various pHs revealed thatkcatfor the PEI derivative prepared by site-directed modification was three to six times greater than that by random modification. The results were taken to indicate thatItransferredIIIto the vicinity of the CD moiety of CD-PEI, but that orientation ofIIIand the CD cavity in the resulting PEI derivative was not very productive for deacylation ofIVcomplexed by the CD cavity." @default.
• W2007069160 created "2016-06-24" @default.
• W2007069160 creator A5041629005 @default.
• W2007069160 creator A5077499223 @default.
• W2007069160 date "1998-08-01" @default.
• W2007069160 modified "2023-10-14" @default.
• W2007069160 title "Artificial Metalloesterases Constructed by Site-Directed Attachment of Oximinato Metal Centers to Poly(ethylenimine) Containing β-Cyclodextrin" @default.
• W2007069160 cites W1547700239 @default.
• W2007069160 cites W1970896935 @default.
• W2007069160 cites W1975541156 @default.
• W2007069160 cites W1982416705 @default.
• W2007069160 cites W1987046770 @default.
• W2007069160 cites W1990496441 @default.
• W2007069160 cites W1991831490 @default.
• W2007069160 cites W1995084805 @default.
• W2007069160 cites W1995325788 @default.
• W2007069160 cites W2015046327 @default.
• W2007069160 cites W2020529530 @default.
• W2007069160 cites W2042269111 @default.
• W2007069160 cites W2043368741 @default.
• W2007069160 cites W2047965417 @default.
• W2007069160 cites W2057263317 @default.
• W2007069160 cites W2073564465 @default.
• W2007069160 cites W2319410995 @default.
• W2007069160 cites W2951571379 @default.
• W2007069160 cites W3004525784 @default.
• W2007069160 cites W3136626997 @default.
• W2007069160 doi "https://doi.org/10.1006/bioo.1998.1090" @default.
• W2007069160 hasPublicationYear "1998" @default.
• W2007069160 type Work @default.
• W2007069160 sameAs 2007069160 @default.
• W2007069160 citedByCount "25" @default.
• W2007069160 countsByYear W20070691602012 @default.
• W2007069160 countsByYear W20070691602013 @default.
• W2007069160 countsByYear W20070691602014 @default.
• W2007069160 countsByYear W20070691602015 @default.
• W2007069160 countsByYear W20070691602017 @default.
• W2007069160 countsByYear W20070691602019 @default.
• W2007069160 countsByYear W20070691602020 @default.
• W2007069160 crossrefType "journal-article" @default.
• W2007069160 hasAuthorship W2007069160A5041629005 @default.
• W2007069160 hasAuthorship W2007069160A5077499223 @default.
• W2007069160 hasConcept C106159729 @default.
• W2007069160 hasConcept C111771559 @default.
• W2007069160 hasConcept C115537861 @default.
• W2007069160 hasConcept C147789679 @default.
• W2007069160 hasConcept C161790260 @default.
• W2007069160 hasConcept C162324750 @default.
• W2007069160 hasConcept C178790620 @default.
• W2007069160 hasConcept C181199279 @default.
• W2007069160 hasConcept C184133267 @default.
• W2007069160 hasConcept C185592680 @default.
• W2007069160 hasConcept C188027245 @default.
• W2007069160 hasConcept C193557335 @default.
• W2007069160 hasConcept C21951064 @default.
• W2007069160 hasConcept C2776568683 @default.
• W2007069160 hasConcept C2779433975 @default.
• W2007069160 hasConcept C41183919 @default.
• W2007069160 hasConcept C544153396 @default.
• W2007069160 hasConcept C71240020 @default.
• W2007069160 hasConcept C94412978 @default.
• W2007069160 hasConceptScore W2007069160C106159729 @default.
• W2007069160 hasConceptScore W2007069160C111771559 @default.
• W2007069160 hasConceptScore W2007069160C115537861 @default.
• W2007069160 hasConceptScore W2007069160C147789679 @default.
• W2007069160 hasConceptScore W2007069160C161790260 @default.
• W2007069160 hasConceptScore W2007069160C162324750 @default.
• W2007069160 hasConceptScore W2007069160C178790620 @default.
• W2007069160 hasConceptScore W2007069160C181199279 @default.
• W2007069160 hasConceptScore W2007069160C184133267 @default.
• W2007069160 hasConceptScore W2007069160C185592680 @default.
• W2007069160 hasConceptScore W2007069160C188027245 @default.
• W2007069160 hasConceptScore W2007069160C193557335 @default.
• W2007069160 hasConceptScore W2007069160C21951064 @default.
• W2007069160 hasConceptScore W2007069160C2776568683 @default.
• W2007069160 hasConceptScore W2007069160C2779433975 @default.
• W2007069160 hasConceptScore W2007069160C41183919 @default.
• W2007069160 hasConceptScore W2007069160C544153396 @default.
• W2007069160 hasConceptScore W2007069160C71240020 @default.
• W2007069160 hasConceptScore W2007069160C94412978 @default.
• W2007069160 hasIssue "2" @default.
• W2007069160 hasLocation W20070691601 @default.
• W2007069160 hasOpenAccess W2007069160 @default.
• W2007069160 hasPrimaryLocation W20070691601 @default.
• W2007069160 hasRelatedWork W1480924375 @default.
• W2007069160 hasRelatedWork W1550634984 @default.
• W2007069160 hasRelatedWork W2074857616 @default.
• W2007069160 hasRelatedWork W2299503928 @default.
• W2007069160 hasRelatedWork W2376082430 @default.
• W2007069160 hasRelatedWork W2390476533 @default.
• W2007069160 hasRelatedWork W2479804469 @default.
• W2007069160 hasRelatedWork W2890264855 @default.
• W2007069160 hasRelatedWork W4210408838 @default.
• W2007069160 hasRelatedWork W2489339783 @default.
• W2007069160 hasVolume "26" @default.
• W2007069160 isParatext "false" @default.
• W2007069160 isRetracted "false" @default.
• W2007069160 magId "2007069160" @default.

• next