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• W2007076215 abstract "Copper iodide has been shown to be an effective cocatalyst for the olefin cross-metathesis reaction. In particular, it has both a catalyst stabilizing effect due to iodide ion, as well as copper(I)-based phosphine-scavenging properties that apply to use of the Grubbs-2 catalyst. A variety of Michael acceptors and olefinic partners can be cross-coupled under mild conditions in refluxing diethyl ether that avoid chlorinated solvents. This effect has also been applied to chemistry in water at room temperature using the new surfactant TPGS-750-M." @default.
• W2007076215 created "2016-06-24" @default.
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• W2007076215 date "2011-04-29" @default.
• W2007076215 modified "2023-10-18" @default.
• W2007076215 title "Rate Enhanced Olefin Cross-Metathesis Reactions: The Copper Iodide Effect" @default.
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• W2007076215 doi "https://doi.org/10.1021/jo200360s" @default.
• W2007076215 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3352770" @default.
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