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- W2007079425 abstract "Premixed flames of perchloric acid with methane that contain an appreciable amount of diluent have been found to exhibit a two-flame structure for a slightly fuel-rich range of fuel/oxidizer ratios. A similar, more diffuse structure is apparent in perchloric acid flames containing less diluent, or with other hydrocarbons. Burning velocities, spectra, temperatures, and burned gas compositions have been measured for flames with methane as fuel. The product analyses indicate that the second flame results from the combustion of carbon monoxide and of a smaller amount of hydrocarbon, which are not oxidized in the first flame. It is concluded that the two flame fronts result from a dual oxidizing action of the perchloric acid in producing both a chloride-oxygen species, which reacts rapidly with the initial fuel molecule, and oxygen, which completes the combustion. The relevance of this finding to other properties of perchloric acid flames is discussed." @default.
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- W2007079425 date "1969-01-01" @default.
- W2007079425 modified "2023-09-24" @default.
- W2007079425 title "Perchloric acid flames: IX. Two-flame structure with hydrocarbons" @default.
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- W2007079425 doi "https://doi.org/10.1016/s0082-0784(69)80481-9" @default.
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