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- W2007079589 abstract "A quantitative examination of the acetone produced from the oxidation of isopropanol by Ag aq II shows that two Ag aq II ions are consumed for each isopropanol molecule, and the kinetics show that the reaction involves the direct attack of an Ag aq II ion on an isopropanol molecule without involving intermediate Ag aq III . The overall reaction is insensitive to change in acidity, as found previously in the oxidation of secondary alcohols by direct attack of Mn aq III . To explain the effect of Ag I on the rate, a back reaction is postulated, analogous to that found previously in the oxidation of methanol by Mn aq III . The free energy, energy and entropy of activation are compared with those found for the oxidation of isopropanol by other cations." @default.
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- W2007079589 date "1976-01-01" @default.
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- W2007079589 title "Kinetics of the oxidation of isopropanol by aquosilver(II) ions in aqueous perchlorate media" @default.
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- W2007079589 doi "https://doi.org/10.1016/0022-1902(76)80410-1" @default.
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