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• W2007081684 abstract "An enantioselective synthesis of (+)-biotin 1 starting from naturally available cysteine is described. The key steps are the unusual stereochemical outcome of radical cyclization of compound 10 to prepare 5,5-fused system 11, and the introduction of C4-sidechain at C6 in 13 via a Grignard reaction." @default.
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• W2007081684 date "2005-09-01" @default.
• W2007081684 modified "2023-10-01" @default.
• W2007081684 title "An unusual stereochemical outcome of radical cyclization: synthesis of (+)-biotin" @default.
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• W2007081684 doi "https://doi.org/10.1016/j.tet.2005.07.070" @default.
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