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- W2007098981 abstract "Chiral amidines and guanidines have potential as enantioselective catalysts for reactions of nitroalkanes, through formation of hydrogen-bonded complexes with nitronate anions. With this in mind, the bicyclic guanidine 9 was synthesized from amino-alcohol 12, employing pyrrole formation as a protection method for the amino-nitrogen. Low enantioselectivities were obtained when 9 was used as catalyst for conjugate additions of nitroalkanes. However, other applications are suggested by its hindered, chiral and strongly basic nature." @default.
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- W2007098981 date "1995-11-01" @default.
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- W2007098981 title "Synthesis and investigation of a hindered, chiral, bicyclic guanidine" @default.
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