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- W2007102347 abstract "The homologous series ${mathrm{HgBa}}_{2}$${mathrm{Ca}}_{mathit{n}mathrm{ensuremath{-}}1}$${mathrm{Cu}}_{mathit{n}}$${mathrm{O}}_{2mathit{n}+2+mathrm{ensuremath{delta}}}$ (n=1,2,3,4) are the newest and most promising of the layered high-${mathit{T}}_{mathit{c}}$ superconducting materials, as demonstrated in setting the highest ${mathit{T}}_{mathit{c}}$ among the known superconducting materials. The first of its series, ${mathrm{HgBa}}_{2}$${mathrm{CuO}}_{4+mathrm{ensuremath{delta}}}$, contains only one Cu-O plane per unit cell and is superconducting with ${mathit{T}}_{mathit{c}}$ about 94 K. The superconducting transition temperature as a function of pressure, ${mathit{T}}_{mathit{c}}$(P), was measured to 4.5 GPa. ${mathit{T}}_{mathit{c}}$ was determined from ac susceptibility measurements and pressure was determined near ${mathit{T}}_{mathit{c}}$ from shifts in ruby fluorescence peaks. ${mathit{T}}_{mathit{c}}$ increases monotonically with ${mathit{dT}}_{mathit{c}}$(P)/dPensuremath{approxeq}1.8 K/GPa at ambient pressure. The volume as a function of pressure, V(P), was measured to 10 GPa. The lattice parameters were determined by energy-dispersive x-ray-diffraction methods and pressure was determined from shifts in ruby fluorescence peaks. The volume decreases monotonically producing an isothermal bulk modulus ${mathit{B}}_{mathit{V}}$=104ifmmodepmelsetextpmfi{}17 GPa at ambient pressure. Both results were combined to produce ${mathit{T}}_{mathit{c}}$(V), which is more readily compared to theoretical models." @default.
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- W2007102347 date "1994-05-01" @default.
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- W2007102347 title "Volume dependence of the superconducting transition temperature for the high-temperature superconductorHgBa2CuO4+δ" @default.
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- W2007102347 doi "https://doi.org/10.1103/physrevb.49.13075" @default.
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