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• W2007104324 abstract "The reaction between periodate and thiourea has been studied in an unbuffered medium. A variety of interesting dynamical behavior including variable stoichiometries, characteristic clock reaction and oligooscillations or single peak oscillations in pH, the concentrations of both iodide and iodine were found in a closed reactor. When studied in an open reactor, the above reaction system displays fascinating damped oscillations and bistability in an unbuffered aqueous solution. A 12-step simplified mechanism has also been proposed here. Our investigation illustrates that it is critical to include a rapid H+-mediated preequilibrium step in the suggested mechanism. The modified mechanism gives a better agreement between the calculated results and experimental observations." @default.
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• W2007104324 date "2008-10-01" @default.
• W2007104324 modified "2023-10-14" @default.
• W2007104324 title "Nonlinear Oxidation of Thiourea in an Unbuffered Medium" @default.
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• W2007104324 doi "https://doi.org/10.1002/cjoc.200890320" @default.
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