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- W2007105687 abstract "Abstract The study of protonation equilibria in the complexes bis(dihydrogenoviolurato)chloronitrosylruthenium and tris(dihydrogenoviolurato)nitrosylruthenium demonstrates the mutual effects of nitrosyl and violurate ligands in the coordination sphere of ruthenium. The very important increasing of the acidity of the deprotonation sites in the coordinated heterocycles is explained by the coordination of the nitrosyl to ruthenium(II). Shifts of metal-to-ligand charge transfer transition bands which give informations about the energy of the molecular orbitals in the ligand violurate accompany the successive deprotonations. Reciprocally, the deprotonated species of coordinated heterocycle constitute as much different coordination environments for the nitrosyl ligand and determine its affinity for nucleophilic agents in general and especially for OH − ." @default.
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- W2007105687 title "Influence reciproque des coordinats nitrosyle et violurate dans les bis(dihydrogenoviolurato)chloronitrosylruthenium et tris(dihydrogenoviolurato)nitrosylruthenium. Echanges protoniques, interconversion nitrosyle-nitrite" @default.
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- W2007105687 doi "https://doi.org/10.1016/0022-1902(76)80464-2" @default.
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