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• W2007115078 startingPage "1472" @default.
• W2007115078 abstract "The functionalized disilane (PhSCH2)Me2SiSiMe2(CH2SPh) (1) has been prepared and coordinated as a dithioether ligand on [PtCl2(PhCN)2] to afford the fluxional seven-membered chelate complex cis-[PtCl2{(PhSCH2)2Si2Me4}] (2a). After metathesis reaction of 2a with NaI the diiodo derivative cis-[PtI2{(PhSCH2)2Si2Me4}] (2b) was obtained. Treatment of [Re(μ-Br)(CO)3THF]2 with 1 equiv of 1 yields the bromo-bridged dinuclear complex fac-[{Re(μ-Br)(CO)3}2{μ-(PhSCH2)2Si2Me4}] (5), which is spanned by 1 forming a 10-membered mesocycle. Addition of a further equivalent of 1 yields the dinuclear macrocyclic compound fac-[{ReBr(CO)3}2{μ-(PhSCH2)2Si2Me4}2] (4), forming a 14-membered ring system. The chloro-bridge of [RuCl(μ-Cl)(CO)3]2 is cleaved by 1 to give the dinuclear compound fac-[{RuCl2(CO)3}2{μ-(PhSCH2)2Si2Me4}] (6), in which the two metal fragments are linked by the thioether functions. In the presence of catalytic amounts of Pd(OAc)2/CNR, the Si−Si bond of 1 is cleaved and addition across the triple bond of phenylacetylene or p-tolylacetylene affords the bis-silylated olefins Z-(PhSCH2)Me2SiC(H)C(Ar)SiMe2(CH2SPh) (7a Ar = Ph; 7b Ar = p-Tol). The new compounds have been studied by multinuclear NMR techniques; the crystal structures of 2a, 2b, 4, 5, 6, and 7a have been determined by X-ray diffraction studies." @default.
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• W2007115078 date "2006-02-11" @default.
• W2007115078 modified "2023-10-17" @default.
• W2007115078 title "1,1,2,2-Tetramethyl-1,2-bis(phenylthiomethyl)disilane, a Flexible Ligand for the Construction of Macrocyclic, Mesocyclic, and Bridged Dithioether Complexes. Synthesis of the Bis-silylated Olefins <i>Z</i>-(PhSCH₂)Me₂SiC(H)C(Ar)SiMe₂(CH₂SPh) by Catalytic Activation of the Si−Si Bond" @default.
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• W2007115078 doi "https://doi.org/10.1021/om0489812" @default.
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