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- W2007116013 abstract "Although no radiation is observable from the fast exothermic reaction N+O3→NO+O2 the addition of H atoms produces a flame with ultraviolet and visible emission. The emitters in the flames are OH, NH, NO, N2 and, under certain conditions, NH2. The characteristics of this prototype combustion system are:o(a)N atoms, H atoms and O3 must all be present in the reaction zone.(b)H atoms catalyze the consumption of ozone beyond that expected from H+O3→OH+O2.(c)NO and NO2 are not important intermediates.(d)The nitrogen emission (1st positive bands) is not the result of the mechanism operating in the Lewis-Rayleigh nitrogen afterglow.(e)Vibrationally excited OH radicals are important in the mechanism for forming NH and in the excitation of the emitters. N atoms, H atoms and O3 must all be present in the reaction zone. H atoms catalyze the consumption of ozone beyond that expected from H+O3→OH+O2. NO and NO2 are not important intermediates. The nitrogen emission (1st positive bands) is not the result of the mechanism operating in the Lewis-Rayleigh nitrogen afterglow. Vibrationally excited OH radicals are important in the mechanism for forming NH and in the excitation of the emitters. The rate constant for the reaction N+OH→NO+H is estimated to be greater than 10−11 cc/molecule-second." @default.
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- W2007116013 title "Atomic flame reactions involving N atoms, H atoms and ozone" @default.
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- W2007116013 doi "https://doi.org/10.1016/s0082-0784(63)80076-4" @default.
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