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- W2007123923 abstract "Homometallic europium(III) and terbium(III) trans-2-butenoate polymers, chemical formulas [{Eu3(MeCHCHCO2)9(H2O)4}·H2O·EtOH]n (1) and [{Tb(MeCHCHCO2)3(H2O)}·MeCHCHCO2H]n (2) and their dimeric 1,10-phenanthroline derivatives [Ln2(MeCHCHCO2)6(phen)2]·2H2O, with Ln=Eu (3) and Tb (4), were prepared and characterized by single-crystal X-ray diffraction. The coordination polymers 1 and 2 adopt different carboxylate-bridged infinite chain structures. While the europium compound 1 shows three independent europium centers linked to each other by three different types and number of carboxylate bridges, the terbium polymer 2 shows one independent metal center bridged by the same type of double carboxylates along the chains. Compounds 3 and 4 are isomorphous dinuclear structures with quadruply bridged carboxylate groups, two in the η1:η1:μ2 and two in the η2:η1:μ2 modes. The magnetic and photophysical behaviors of the four compounds are reported in the solid state." @default.
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- W2007123923 date "2003-11-01" @default.
- W2007123923 modified "2023-10-09" @default.
- W2007123923 title "Europium(III) and terbium(III) trans-2-butenoates: syntheses, crystal structures, and properties" @default.
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- W2007123923 doi "https://doi.org/10.1016/s0020-1693(03)00250-0" @default.
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