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- W2007124522 abstract "Abstract Fe x Ni 1− x nanostructures with different compositions (0 x x Ni 1− x nanostructures were systematically investigated. As the composition of Fe ( x ) in Fe x Ni 1− x nanostructures decreased from 1.0 to 0, the morphology changed from dendritic to nanoparticles and thin plates. The X-ray diffraction (XRD) patterns revealed that the dominant crystal structures shifted from metallic body centered cubic (bcc) for iron-rich Fe x Ni 1− x to mixed bcc and faced center cubic (fcc) for near equiatomic FeNi to rhombohedral/hexagonal for nickel-rich FeNi. The magnetic saturation and isoelectric point were also strongly dependent on nanostructure composition. Specifically, the magnetic saturation decreased and the isoelectric point increased with decreasing Fe content. When Fe content in Fe x Ni 1− x nanostructures was greater than 0.5 ( x > 0.5), Fe x Ni 1− x nanostructures showed mainly metallic (zero-valent) Fe present as determined by XRD and selected area electron diffraction (SAED) patterns. Accordingly, Fe 1.0 , Fe 0.71 Ni 0.29 and Fe 0.55 Ni 0.45 exhibited reactivity toward 1,1,1,2-tetrachloroethane, with Fe 1.0 yielding the greatest rate of reductive dechlorination." @default.
- W2007124522 created "2016-06-24" @default.
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- W2007124522 date "2009-08-01" @default.
- W2007124522 modified "2023-09-27" @default.
- W2007124522 title "Electrochemical synthesis of FexNi1−x nanostructures for environmental remediation" @default.
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- W2007124522 doi "https://doi.org/10.1016/j.cej.2009.01.048" @default.
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