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- W2007124814 abstract "Abstract Equilibrium studies on mixed ligand complexes of some bivalent metal ions, viz., Cu(II), Zn(II), Cd(II), Co(II), or Ni(II) with 2,2′-bipyridyl (Bpy) or 1,10-phenanthroline (Phen) as primary ligand and N-methylaminothioformyl-N′-phenylhydroxylamine (MATPH) as secondary ligand have been made using the Irving-Rossotti pH titration method in 50% aqueous-dioxane medium at 35 ± 0.5° C and 0.1 M (NaClO4) ionic strength in an inert atmosphere. Formation constants, characteristic of mixed ligand complexes, have been calculated in the system M + A → MA; MA + L → MAL where M = Cu(II), Zn(II), Cd(II), Co(II), or Ni(II); A = 2,2′-bipyridyl or 1,10-phenanthroline, L = N-methylaminothioformyl-N′-phenyl-hydroxylamine. In all the systems, the Δ log KM values are negative which is due to the discriminating qualities of the heteroaromatic N-base. It is suggested that the S-ligand may also have π -accepting qualities with a greater influence on the stability of the complexes, Further results indicate that MATPH and Bpy or Phen are incompatible ligands toward the metal ions mentioned above and hence the mixed ligand complexes formed have lower stability than binary complexes of MATPH." @default.
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- W2007124814 title "Equilibrium Studies on Mixed Ligand Complexes of Some Bivalent Metal Ions with 2,2′-Bipyridyl or 1,10-Phenanthroline and N-Methylaminothioformyl-N′-phenylhydroxylamine" @default.
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- W2007124814 doi "https://doi.org/10.1080/00222338108063251" @default.
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