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- W2007129627 abstract "Reflection adsorption infrared spectroscopy has been used to show that the same surface species forms on Cu(100) from the thermal decomposition of isocyanic acid (HNCO) and from the reaction of cyanogen (C2N2) with preadsorbed oxygen. This species is identified as isocyanate, NCO, linearly bonded to the surface through the nitrogen atom. It is characterized by an intense band due to the asymmetric NCO stretch at 2201 cm−1, a very weak band at 1321 cm−1 due to the symmetric NCO stretch, and a very weak band at 3448 cm−1 due to the symmetric stretch plus asymmetric stretch combination band. Isotopic substitution with13C,15N, and 18O supports the assignment. Isocyanate is stable on Cu(100) up to 500 K." @default.
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- W2007129627 date "1997-12-01" @default.
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- W2007129627 title "Formation of isocyanate on Cu(100) from the oxidation of cyanogen and from the decomposition of isocyanic acid" @default.
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- W2007129627 doi "https://doi.org/10.1016/s0039-6028(97)00802-9" @default.
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