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- W2007131344 abstract "Abstract The infrared spectrum of aniline–water–pyrrole cluster cation has been measured in the 3 μm region. Four strong vibrational bands were observed at 3313, 3515, 3637, and 3721 cm −1 , and the cluster dissociated into fragments in two reaction paths, AWP+→AW++P and AWP+→AP++W (A: aniline, W: water, P: pyrrole) when it absorbed an infrared photon. The branching ratio (AW+/AP+) has been determined to be 0.20±0.02 for the NH stretching vibration of aniline ( 3313 cm −1 , hydrogen-bonded to pyrrole) and 0.14±0.03 for the other three bands. This vibrational mode dependence should be due to the fast energy transfer from the NH to the intermolecular vibration through the hydrogen bond." @default.
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- W2007131344 date "2001-10-01" @default.
- W2007131344 modified "2023-09-23" @default.
- W2007131344 title "The evidence of the mode selectivity of the infrared predissociation reaction of the hydrogen bonds in the aniline–water–pyrrole cluster cation" @default.
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- W2007131344 doi "https://doi.org/10.1016/s0009-2614(01)00989-7" @default.
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