Matches in SemOpenAlex for { <https://semopenalex.org/work/W2007140458> ?p ?o ?g. }
- W2007140458 endingPage "2770" @default.
- W2007140458 startingPage "2763" @default.
- W2007140458 abstract "Using a split-valence Gaussian 4-31G basis function augmented with diffuse p and d function and multiconfiguration self-consistent-field optimized geometries, the frequency-dependent polarizability ensuremath{alpha} and second hyperpolarizability ensuremath{gamma} of ethylene, trans-butadiene, trans-hexatriene, and trans-octatetraene molecules have been calculated by the time-dependent coupled perturbed Hartree-Fock ab initio method. The calculated values of ensuremath{alpha} and ensuremath{gamma} are in good agreement with the corresponding gas-phase experimental values at the same fundamental wavelength. The various ensuremath{gamma} values corresponding to different third-order processes exhibit marked difference in their dependence on the conjugation length. For a specific fundamental frequency, the calculated ensuremath{gamma} value exhibits the following order: ensuremath{gamma}(-3ensuremath{omega};ensuremath{omega},ensuremath{omega},ensuremath{omega})>ensuremath{gamma}(-2ensuremath{omega};0,ensuremath{omega},ensuremath{omega})>ensuremath{gamma}(-ensuremath{omega};ensuremath{omega},ensuremath{omega},-ensuremath{omega}) >ensuremath{gamma}(-ensuremath{omega};0,0,ensuremath{omega})ensuremath{approxeq}ensuremath{gamma}(0;0,ensuremath{omega},-ensuremath{omega})." @default.
- W2007140458 created "2016-06-24" @default.
- W2007140458 creator A5045801673 @default.
- W2007140458 creator A5046813112 @default.
- W2007140458 creator A5047222222 @default.
- W2007140458 creator A5051938234 @default.
- W2007140458 date "1992-03-01" @default.
- W2007140458 modified "2023-10-14" @default.
- W2007140458 title "Frequency dependence of linear and nonlinear optical properties of conjugated polyenes: An<i>ab initio</i>time-dependent coupled Hartree-Fock study" @default.
- W2007140458 cites W1977467190 @default.
- W2007140458 cites W1977641754 @default.
- W2007140458 cites W1980979516 @default.
- W2007140458 cites W1981232347 @default.
- W2007140458 cites W1985779401 @default.
- W2007140458 cites W1986465334 @default.
- W2007140458 cites W1988443050 @default.
- W2007140458 cites W1992578750 @default.
- W2007140458 cites W1997694672 @default.
- W2007140458 cites W2001334971 @default.
- W2007140458 cites W2002313887 @default.
- W2007140458 cites W2012077910 @default.
- W2007140458 cites W2014451764 @default.
- W2007140458 cites W2015146538 @default.
- W2007140458 cites W2022058934 @default.
- W2007140458 cites W2027011380 @default.
- W2007140458 cites W2031168255 @default.
- W2007140458 cites W2037704740 @default.
- W2007140458 cites W2037726979 @default.
- W2007140458 cites W2039325260 @default.
- W2007140458 cites W2039853765 @default.
- W2007140458 cites W2040071340 @default.
- W2007140458 cites W2043692545 @default.
- W2007140458 cites W2055987664 @default.
- W2007140458 cites W2058954595 @default.
- W2007140458 cites W2072389754 @default.
- W2007140458 cites W2079611495 @default.
- W2007140458 cites W2082234179 @default.
- W2007140458 cites W2088696020 @default.
- W2007140458 cites W2092614420 @default.
- W2007140458 cites W2093705768 @default.
- W2007140458 cites W2093723510 @default.
- W2007140458 cites W2095171685 @default.
- W2007140458 cites W2097247545 @default.
- W2007140458 doi "https://doi.org/10.1103/physreva.45.2763" @default.
- W2007140458 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/9907306" @default.
- W2007140458 hasPublicationYear "1992" @default.
- W2007140458 type Work @default.
- W2007140458 sameAs 2007140458 @default.
- W2007140458 citedByCount "62" @default.
- W2007140458 countsByYear W20071404582016 @default.
- W2007140458 countsByYear W20071404582017 @default.
- W2007140458 countsByYear W20071404582021 @default.
- W2007140458 crossrefType "journal-article" @default.
- W2007140458 hasAuthorship W2007140458A5045801673 @default.
- W2007140458 hasAuthorship W2007140458A5046813112 @default.
- W2007140458 hasAuthorship W2007140458A5047222222 @default.
- W2007140458 hasAuthorship W2007140458A5051938234 @default.
- W2007140458 hasConcept C10138342 @default.
- W2007140458 hasConcept C121332964 @default.
- W2007140458 hasConcept C139287275 @default.
- W2007140458 hasConcept C162324750 @default.
- W2007140458 hasConcept C182306322 @default.
- W2007140458 hasConcept C183971685 @default.
- W2007140458 hasConcept C184779094 @default.
- W2007140458 hasConcept C2779557605 @default.
- W2007140458 hasConcept C2780694488 @default.
- W2007140458 hasConcept C2781442258 @default.
- W2007140458 hasConcept C32909587 @default.
- W2007140458 hasConcept C62520636 @default.
- W2007140458 hasConceptScore W2007140458C10138342 @default.
- W2007140458 hasConceptScore W2007140458C121332964 @default.
- W2007140458 hasConceptScore W2007140458C139287275 @default.
- W2007140458 hasConceptScore W2007140458C162324750 @default.
- W2007140458 hasConceptScore W2007140458C182306322 @default.
- W2007140458 hasConceptScore W2007140458C183971685 @default.
- W2007140458 hasConceptScore W2007140458C184779094 @default.
- W2007140458 hasConceptScore W2007140458C2779557605 @default.
- W2007140458 hasConceptScore W2007140458C2780694488 @default.
- W2007140458 hasConceptScore W2007140458C2781442258 @default.
- W2007140458 hasConceptScore W2007140458C32909587 @default.
- W2007140458 hasConceptScore W2007140458C62520636 @default.
- W2007140458 hasIssue "5" @default.
- W2007140458 hasLocation W20071404581 @default.
- W2007140458 hasLocation W20071404582 @default.
- W2007140458 hasOpenAccess W2007140458 @default.
- W2007140458 hasPrimaryLocation W20071404581 @default.
- W2007140458 hasRelatedWork W1638955569 @default.
- W2007140458 hasRelatedWork W1974316225 @default.
- W2007140458 hasRelatedWork W1997263767 @default.
- W2007140458 hasRelatedWork W2004501070 @default.
- W2007140458 hasRelatedWork W2030784237 @default.
- W2007140458 hasRelatedWork W2034006637 @default.
- W2007140458 hasRelatedWork W2040283723 @default.
- W2007140458 hasRelatedWork W2080078245 @default.
- W2007140458 hasRelatedWork W2172069867 @default.
- W2007140458 hasRelatedWork W2313029283 @default.
- W2007140458 hasVolume "45" @default.
- W2007140458 isParatext "false" @default.