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• W2007151507 abstract "Fluorescence lifetimes of 33 alkanes were measured at 25°C using a 0.7 ns pulse radiolysis system and the relationship between molecular structure, fluorescence lifetime (τ), quantum yield (Φf) and radiative rate constant (R = Φfτ) is discussed. The τ's showed a large dependence on the molecular structure, however, the R-values were approximately constant for groups of alkanes: R = 1.3×106 s−1 for n-alkanes, R ≈ 4×106 s−1 for aliphatic vicinally substituted dimethyl alkanes, R = 7×106 s-1 for cyclohexane and alkylcyclohexanes, and R = 10×106 s−1 for di- and trimethylcyclohexanes. The excited state lifetimes of some non-fluorescing alkanes were also determined from steady-state photolytic quenching data and found to be very low (⩽ 0.3 ns)." @default.
• W2007151507 created "2016-06-24" @default.
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• W2007151507 date "1985-03-01" @default.
• W2007151507 modified "2023-09-23" @default.
• W2007151507 title "Fluorescence lifetimes and radiative rate constants of alkanes at 25°C" @default.
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• W2007151507 doi "https://doi.org/10.1016/0022-2313(85)90030-4" @default.
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