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- W2007155166 abstract "In the concentrated solutions of CuCl2/HCl/H2O examined in this study, Cu2+ has tetragonally distorted octahedral coordination on the average. In these solutions of ca. 2 molar concentration, solute association does not appear to be an important solution parameter. In all of the solutions, the linear ClaxCuClax network remains intact upon dissolution of anhydrous copper(II) chloride. Ligand occupation of the equatorial coordination sites apparently is dependent upon the chloride/copper and/or the water/chloride stoichiometric ratios in each solution. The Cu-ligand bond distances are calculated to be: CuOeq, 1·95 Å; CuCleq, 2·35 Å; and CuClax, 2·8 Å. The latter two distances are significantly different than those calculated for the highly associated solute species found in aqueous solutions of CuCl2[1]." @default.
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- W2007155166 title "Effect of hydrochloric acid on the mean solute species in copper(II) chloride/hydrochloric acid solutions" @default.
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- W2007155166 doi "https://doi.org/10.1016/0022-1902(74)80071-0" @default.
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