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• W2007173306 abstract "The synthesis, characterization and study of the new ferrocenyl Schiff base: [η5-C5H5)Fe(η5-C5H4)-CH=N-CH2-CH2-N(CH3)2] (1) is reported. This substrate reacts with Na2[PdCl4] or with transition metal dichlorides MCl2 · nH2O with M = Zn, Ni, Co or Cu giving the corresponding coordination compounds: [M(η5-C5H5)Fe[(η5-C5H4)-CH=N-CH2-CH2-N(CH3)2]Cl2] with M = Pd (2), Zn (3), Ni (4), Co (5), and Cu (6). These heterobimetallic compounds have been characterized by infrared and UV—visible spectroscopies. NMR-spectroscopic studies on the diamagnetic derivatives (1–3) together with magnetochemical studies on the paramagnetic species (4–6) are also reported. Crystals of complex 3 have also been characterized by X-ray diffraction: orthorhombic space group Pcab, with a = 12.225(1) Å; b = 14.685(1) Å; c = 19.474(1) Å, and V = 3498.4(4) Å3. Electrochemical studies, based on cyclic voltammetry, for all the compounds have allowed us to establish the influence of the central atom M(II) upon the redox ability of the Fe(II)." @default.
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• W2007173306 date "1997-10-01" @default.
• W2007173306 modified "2023-10-16" @default.
• W2007173306 title "Syntheses, characterization and study of the properties of heterobimetallic compounds containing ferrocenyl units X-ray crystal structure of: [Zn(η5-C5H5)Fe[(η5-C5H4)-CH=N-CH2-CH2-N(CH3)2]Cl2]" @default.
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• W2007173306 doi "https://doi.org/10.1016/s0022-328x(97)00298-2" @default.
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