FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2007175030> ?p ?o ?g. }

• W2007175030 endingPage "2386" @default.
• W2007175030 startingPage "2377" @default.
• W2007175030 abstract "Ambient-temperature photolysis of the aminoborylene complex [(OC)5CrBN(SiMe3)2] in the presence of a series of trans-bis(alkynyl)platinum(II) precursors of the type trans-[Pt(CCAr)2(PEt3)2] (Ar=Ph, p-C6H4OMe, and p-C6H4CF3) successfully leads to twofold transfer of the borylene moiety [:BN(SiMe3)2] onto the alkyne functionalities. The alkynyl precursors and resultant bis(borirene)platinum(II) complexes formed are of the type trans-[Pt(B{N(SiMe3)2}CCAr)2(PEt3)2] (Ar=Ph, p-C6H4OMe, and p-C6H4CF3). These species have all been successfully characterized by NMR, IR, and UV/Vis spectroscopy as well as by elemental analysis. Single-crystal X-ray diffraction has verified that these trans-bis(borirene)platinum(II) complexes display coplanarity between the twin three-membered rings across the platinum core in the solid state and stand as the first examples of coplanar conformations of twin borirene systems. These complexes were modeled using density functional theory (DFT), providing information helpful in determining the ability of the transition metal core to interact with each individual borirene ring system and allowing for the observed coplanarity of these rings in the solid state. This proposed transition metal interaction with the twin borirene systems is manifested in the electronic characterization of these borirene species, which display divergent photophysical UV/Vis spectroscopic profiles compared to a previously published mono(borirene)platinum(II) complex." @default.
• W2007175030 created "2016-06-24" @default.
• W2007175030 creator A5004323719 @default.
• W2007175030 creator A5011223450 @default.
• W2007175030 creator A5015756937 @default.
• W2007175030 creator A5038029240 @default.
• W2007175030 creator A5056569207 @default.
• W2007175030 creator A5063568462 @default.
• W2007175030 creator A5084536262 @default.
• W2007175030 creator A5085383509 @default.
• W2007175030 date "2014-11-27" @default.
• W2007175030 modified "2023-09-27" @default.
• W2007175030 title "Platinum<i>trans</i>-Bis(borirene) Complexes Displaying Coplanarity and Communication Across a Platinum Metal Center" @default.
• W2007175030 cites W116545228 @default.
• W2007175030 cites W1492841978 @default.
• W2007175030 cites W1529279120 @default.
• W2007175030 cites W1553330920 @default.
• W2007175030 cites W1968818053 @default.
• W2007175030 cites W1968962542 @default.
• W2007175030 cites W1970209677 @default.
• W2007175030 cites W1971363313 @default.
• W2007175030 cites W1973400133 @default.
• W2007175030 cites W1976669449 @default.
• W2007175030 cites W1983794742 @default.
• W2007175030 cites W1985835147 @default.
• W2007175030 cites W1987812522 @default.
• W2007175030 cites W1989540267 @default.
• W2007175030 cites W1993823535 @default.
• W2007175030 cites W1995340271 @default.
• W2007175030 cites W1996919984 @default.
• W2007175030 cites W1997690495 @default.
• W2007175030 cites W1998088400 @default.
• W2007175030 cites W2001056479 @default.
• W2007175030 cites W2008192551 @default.
• W2007175030 cites W2009961544 @default.
• W2007175030 cites W2010803896 @default.
• W2007175030 cites W2011822711 @default.
• W2007175030 cites W2014434005 @default.
• W2007175030 cites W2014705651 @default.
• W2007175030 cites W2016901060 @default.
• W2007175030 cites W2017580294 @default.
• W2007175030 cites W2019490516 @default.
• W2007175030 cites W2019512570 @default.
• W2007175030 cites W2021408106 @default.
• W2007175030 cites W2022395735 @default.
• W2007175030 cites W2025635001 @default.
• W2007175030 cites W2029449274 @default.
• W2007175030 cites W2032747947 @default.
• W2007175030 cites W2036155485 @default.
• W2007175030 cites W2036297858 @default.
• W2007175030 cites W2039551442 @default.
• W2007175030 cites W2041035154 @default.
• W2007175030 cites W2041277595 @default.
• W2007175030 cites W2041623685 @default.
• W2007175030 cites W2043872748 @default.
• W2007175030 cites W2047165756 @default.
• W2007175030 cites W2048918592 @default.
• W2007175030 cites W2051411840 @default.
• W2007175030 cites W2053053575 @default.
• W2007175030 cites W2056016446 @default.
• W2007175030 cites W2056111309 @default.
• W2007175030 cites W2057343280 @default.
• W2007175030 cites W2059153051 @default.
• W2007175030 cites W2059587016 @default.
• W2007175030 cites W2060364107 @default.
• W2007175030 cites W2061884363 @default.
• W2007175030 cites W2062524885 @default.
• W2007175030 cites W2063131088 @default.
• W2007175030 cites W2063715453 @default.
• W2007175030 cites W2066433440 @default.
• W2007175030 cites W2066850164 @default.
• W2007175030 cites W2069443901 @default.
• W2007175030 cites W2072114851 @default.
• W2007175030 cites W2073424172 @default.
• W2007175030 cites W2075092220 @default.
• W2007175030 cites W2075257456 @default.
• W2007175030 cites W2075888866 @default.
• W2007175030 cites W2077659062 @default.
• W2007175030 cites W2084201747 @default.
• W2007175030 cites W2084392276 @default.
• W2007175030 cites W2091258582 @default.
• W2007175030 cites W2091511348 @default.
• W2007175030 cites W2092451460 @default.
• W2007175030 cites W2095729335 @default.
• W2007175030 cites W2098451383 @default.
• W2007175030 cites W2102890851 @default.
• W2007175030 cites W2114125945 @default.
• W2007175030 cites W2117905866 @default.
• W2007175030 cites W2118979819 @default.
• W2007175030 cites W2121715335 @default.
• W2007175030 cites W2122746064 @default.
• W2007175030 cites W2122973028 @default.
• W2007175030 cites W2124249145 @default.
• W2007175030 cites W2127883769 @default.
• W2007175030 cites W2133300466 @default.
• W2007175030 cites W2133936891 @default.
• W2007175030 cites W2140449259 @default.
• W2007175030 cites W2141269297 @default.

• next