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- W2007178655 abstract "Part I. Experimental procedure. A three meter focal length vacuum spectrograph, designed by Professor J. J. Hopfield, has been constructed at the University of California and used to photograph the extreme ultraviolet hydrogen band spectra. A description of the type of mounting and method used to focus the instrument is given. The greater dispersion and resolving power has made possible the measuring of additional lines. New tables of frequencies are given.Part II. Lines in sixty-eight bands have been given quantum assignments. On the basis of the old quantum theory the moment of inertia of the hydrogen in the normal ($A$ level) state is found to be 0.4673ifmmodetimeselsetexttimesfi{}${10}^{ensuremath{-}40}$ g ${mathrm{cm}}^{2}$ and the nuclear separation to be 0.7500ifmmodetimeselsetexttimesfi{}${10}^{ensuremath{-}8}$ cm. In the first electronic excited state ($B$ level) the moment of inertia is 1.4225ifmmodetimeselsetexttimesfi{}${10}^{ensuremath{-}40}$ g ${mathrm{cm}}^{2}$ and the nuclear separation 1.308ifmmodetimeselsetexttimesfi{}${10}^{ensuremath{-}8}$ cm. Comparison of the present results with those obtained by Richardson and Davidson in their study of bands found in the visible leaves no doubt but that the ultraviolet $B$ state also is the lower state of the bands studied by them. This, then, verifies the assumption made by Birge and leads to the conclusion that the ionization potential of ${mathrm{H}}_{2}$ must be 15.34 volts to within a few hundredths of a volt.Bands connected with vibrational levels ${A}_{0}{A}_{1}$ and ${A}_{2}$ are not observed. In order to obtain the best possible value of ${I}_{0}$, data from all available sources were correlated and averaged. Birge and Jeppesen calculated accurate values of ${B}_{0}$ and ${B}_{1}$, for the normal level, from Rasetti's data on the Raman effect of gaseous hydrogen. Values for ${B}_{1}$ by the two methods agree to one part in seven thousand but their value for ${B}_{0}$ is 0.27 percent higher than the value given by the present method. This discrepancy points to an irregularity in the moment of inertia of hydrogen in the $v=0$ state of the normal electronic level, as has been pointed out by Birge and Jeppesen." @default.
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- W2007178655 date "1930-07-15" @default.
- W2007178655 modified "2023-09-26" @default.
- W2007178655 title "The Resonance (B−A) Band System of the Hydrogen Molecule" @default.
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- W2007178655 doi "https://doi.org/10.1103/physrev.36.187" @default.
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