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- W2007185514 abstract "Trivalent ions of Fe, Cr and Mo are easily incorporated into CsCl-type lattices. Evidently their geometries partly derive from those for divalent ions by exchange of a neutral molecule by hydroxyl or halide. In the ammonium halides hydrogen bonding manifests itself in predominance of low site symmetries and dynamic effects. Evidence for interstitial incorporation of di- and trivalent ions in quartz and isomorphous ABO4 compounds is also presented. EPR data for Fe3+ indicate simultaneous incorporation of O2− or OH− in the c-axis channels. A kinetic reason for preferred interstitial incorporation is proposed. Enhanced mobilities of these as well as certain main constituents may also enhance the reactivities." @default.
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- W2007185514 date "1986-08-01" @default.
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- W2007185514 title "Interstitial Transition Metal Impurities as a Possible Cause of Enhanced Reactivities" @default.
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- W2007185514 doi "https://doi.org/10.1002/bbpc.19860900815" @default.
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