Matches in SemOpenAlex for { <https://semopenalex.org/work/W2007193630> ?p ?o ?g. }
Showing items 1 to 86 of
86
with 100 items per page.
- W2007193630 endingPage "308" @default.
- W2007193630 startingPage "304" @default.
- W2007193630 abstract "Thermodynamics for the binding of electrolyte cations, in particular, tetraalkylammonium ions, to the electrogenerated radical anion and the dianion of the fullerene moieties in a molecular-bilayer membrane film of C60-bearing artificial lipid, 1, cast on an electrode surface was described. The theoretical treatment predicts a linear relationship between the half-wave potential (E1/2) for the electrode reaction and electrolyte concentration in the film (c) at higher concentrations and enables us to obtain the number of bound cation and binding constant, respectively, from the slope and intercept of the E1/2−ln c plot. We measured differential pulse voltammograms for a cast film of 1 on a basal plane graphite electrode in aqueous solution containing tetraethylammonium chloride (or tetra-n-butylammonium chloride) + KCl = 0. 5 M and found that E1/2−ln cs plots for the modified electrodes are linear in a concentration range of ca. 0.002−0.14 M, where cs is the concentration of ammonium electrolytes in the solution phase. The analysis of the plot reveals that the fullerene radical anion forms a 1:1 complex with both tetraethylammonium and tetra-n-butylammonium cations and that the fullerene dianion forms a 1:2 complex with tetra-n-butylammonium cations. The binding constants K1 for the binding of tetraethylammonium and tetra-n-butylammonium cations to radical anions of the fullerene moieties was determined to be 7.93 × 103 and 1.71 × 108 M-1, respectively, provided that the partition coefficients (c/cs) of the tetraalkylammonium ions are unity." @default.
- W2007193630 created "2016-06-24" @default.
- W2007193630 creator A5005651563 @default.
- W2007193630 creator A5014693684 @default.
- W2007193630 creator A5038064077 @default.
- W2007193630 creator A5049928137 @default.
- W2007193630 date "1998-12-30" @default.
- W2007193630 modified "2023-10-18" @default.
- W2007193630 title "Aqueous Electrochemistry of a C<sub>60</sub>-Bearing Artificial Lipid Bilayer Membrane Film Immobilized on an Electrode Surface: Thermodynamics for the Binding of Tetraalkylammonium Ion to the Fullerene Anion" @default.
- W2007193630 cites W1594337171 @default.
- W2007193630 cites W1972746619 @default.
- W2007193630 cites W1979104455 @default.
- W2007193630 cites W1983851964 @default.
- W2007193630 cites W1993445909 @default.
- W2007193630 cites W2000023850 @default.
- W2007193630 cites W2014787579 @default.
- W2007193630 cites W2020016293 @default.
- W2007193630 cites W2021193208 @default.
- W2007193630 cites W2076595992 @default.
- W2007193630 cites W2078000526 @default.
- W2007193630 cites W2298649532 @default.
- W2007193630 cites W655658629 @default.
- W2007193630 doi "https://doi.org/10.1021/jp9833101" @default.
- W2007193630 hasPublicationYear "1998" @default.
- W2007193630 type Work @default.
- W2007193630 sameAs 2007193630 @default.
- W2007193630 citedByCount "41" @default.
- W2007193630 countsByYear W20071936302012 @default.
- W2007193630 countsByYear W20071936302013 @default.
- W2007193630 countsByYear W20071936302015 @default.
- W2007193630 countsByYear W20071936302018 @default.
- W2007193630 countsByYear W20071936302019 @default.
- W2007193630 countsByYear W20071936302020 @default.
- W2007193630 countsByYear W20071936302021 @default.
- W2007193630 crossrefType "journal-article" @default.
- W2007193630 hasAuthorship W2007193630A5005651563 @default.
- W2007193630 hasAuthorship W2007193630A5014693684 @default.
- W2007193630 hasAuthorship W2007193630A5038064077 @default.
- W2007193630 hasAuthorship W2007193630A5049928137 @default.
- W2007193630 hasConcept C147789679 @default.
- W2007193630 hasConcept C162862793 @default.
- W2007193630 hasConcept C17525397 @default.
- W2007193630 hasConcept C178790620 @default.
- W2007193630 hasConcept C179104552 @default.
- W2007193630 hasConcept C184651966 @default.
- W2007193630 hasConcept C185592680 @default.
- W2007193630 hasConcept C18787249 @default.
- W2007193630 hasConcept C2779896888 @default.
- W2007193630 hasConcept C2781295685 @default.
- W2007193630 hasConcept C517785266 @default.
- W2007193630 hasConcept C52859227 @default.
- W2007193630 hasConcept C68801617 @default.
- W2007193630 hasConceptScore W2007193630C147789679 @default.
- W2007193630 hasConceptScore W2007193630C162862793 @default.
- W2007193630 hasConceptScore W2007193630C17525397 @default.
- W2007193630 hasConceptScore W2007193630C178790620 @default.
- W2007193630 hasConceptScore W2007193630C179104552 @default.
- W2007193630 hasConceptScore W2007193630C184651966 @default.
- W2007193630 hasConceptScore W2007193630C185592680 @default.
- W2007193630 hasConceptScore W2007193630C18787249 @default.
- W2007193630 hasConceptScore W2007193630C2779896888 @default.
- W2007193630 hasConceptScore W2007193630C2781295685 @default.
- W2007193630 hasConceptScore W2007193630C517785266 @default.
- W2007193630 hasConceptScore W2007193630C52859227 @default.
- W2007193630 hasConceptScore W2007193630C68801617 @default.
- W2007193630 hasIssue "2" @default.
- W2007193630 hasLocation W20071936301 @default.
- W2007193630 hasOpenAccess W2007193630 @default.
- W2007193630 hasPrimaryLocation W20071936301 @default.
- W2007193630 hasRelatedWork W153398083 @default.
- W2007193630 hasRelatedWork W1997512083 @default.
- W2007193630 hasRelatedWork W2028439467 @default.
- W2007193630 hasRelatedWork W2063513285 @default.
- W2007193630 hasRelatedWork W2068568560 @default.
- W2007193630 hasRelatedWork W2091719394 @default.
- W2007193630 hasRelatedWork W2106686636 @default.
- W2007193630 hasRelatedWork W2107134318 @default.
- W2007193630 hasRelatedWork W2319609032 @default.
- W2007193630 hasRelatedWork W2944702413 @default.
- W2007193630 hasVolume "103" @default.
- W2007193630 isParatext "false" @default.
- W2007193630 isRetracted "false" @default.
- W2007193630 magId "2007193630" @default.
- W2007193630 workType "article" @default.