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- W2007203085 abstract "Pt[P(t-Bu)3]2 (I) is prepared in high yield from a facile reaction of P(t-Bu)3 with K2PtCl4. Its oxidative addition reactions with CHCl3, CH2Cl2, MeI, and I2, and substitution reactions with CO, M(CO)6 (M=Cr, Mo, W), and t-BuNC have been investigated. Reaction with CHCl3 affords trans-PtHCl[P(t-Bu)3]2 (II) and [Pt(µ−Cl){P(t−Bu)2CMe2C︹H2}]2 (III), and reaction with CH2Cl2 yields PtCl{P(t−Bu)2CMe2C︹H2}P(t-Bu)3 (IV). Pt2Me2(μ-I)2[P(t-Bu)3]2 (VI) and P(t-Bu)3-MeI are formed in the reaction of I with MeI. VI undergoes intramolecular metalation to give [Pt(µ−I){P(t−Bu)2CMe2C︹H2}]2 (V), and CH4. Reaction of I with I2 results in the formation of V, trans-PtHI[P(t-Bu)3]2 (VII) and P(t-Bu)3I2. CO readily displaces one phosphine from I to give Pt3[P(t-Bu)3]3(CO)3 (VIII). I reacts with M(CO)6 to afford VIII and M(CO)5P(t-Bu)3. t-BuNC replaces both the phosphines from I to give Pt3(t-BuNC)3(μ-t-BuNC)3 (IX)." @default.
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- W2007203085 date "1981-07-01" @default.
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- W2007203085 title "A convenient synthesis of bis(tri-t-butylphosphine)platinum(0) and its oxidative addition and ligand exchange reactions" @default.
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- W2007203085 doi "https://doi.org/10.1016/s0022-328x(81)80015-0" @default.
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