FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2007207512> ?p ?o ?g. }

• W2007207512 endingPage "600" @default.
• W2007207512 startingPage "565" @default.
• W2007207512 abstract "A combined experimental and theoretical study of the gas-phase thermochemical properties of bicarbonate ion HOCO−2, bisulfite ion HOSO−2, and their conjugate acids is presented. The formation and qualitative identification of the sulfonate ion HSO−3 is also reported. Threshold energies for collision- induced dissociation of OH− ion from HOCO−2 and HOSO−2 have been determined to be 50.3 ± 2.5 and 61.3 ± 2.5 kcal mol−1 respectively, from which the standard heats of formation ΔH°f,298 [HOCO−2, g] = −177.8 ± 2.5 kcal mol−1 and δH°f,298 [HOSO−2] = −165.6 ± 2.5 kcal mol−1 are derived by means of simple thermochemical cycles. The measured HO− binding energies of CO2 and SO2 are in good agreement with ab initio calculations and with the expected values based on empirical correlations between Brönsted and Lewis basicities of negative ions. Reactions between bicarbonate ion and a series of neutral acids in the flowing afterglow indicate an apparent proton affinity of 356 ± 2 kcal mol−1. Bicarbonate ion reacts with H2S to produce both HS− and HS−(H2O), and the deuterium-labelled ion, DOCO−2, reacts also by H/D exchange. Bisulfite ion is found to have an apparent proton affinity of 337 ± 3 kcal mol−1 from its behavior in proton transfer reactions with a series of reference acids. The reaction between HOSO−2 and HCl yields Cl−(SO2) as the major ionic product, along with a small amount of Cl−. DOSO−2 does not exhibit any H/D exchange with HCl or carboxylic acids. Sulfonate ion can be formed at room temperature in the flowing afterglow either by oxygen atom transfer from NO2 to HSO−2, or by hydride transfer from CH3O− to SO3. High level ab initio calculations predict gas-phase acidities (ΔHacid) for carbonic acid (HO)2CO and sulfurous acid (HO)2SO of 339 and 330 kcal mol−1 respectively, and enthalpy changes for their dehydration of −5 and −2kcal mol−1 respectively. The origin of the large differences between the calculated and apparent basicities of HOCO−2 and HOSO−2 is proposed to be due, in part, to a dissociative neutralization mechanism wherein dehydration of the nascent carbonic acid and sulfurous acid molecules accompanies proton transfer." @default.
• W2007207512 created "2016-06-24" @default.
• W2007207512 creator A5050147955 @default.
• W2007207512 date "1992-09-01" @default.
• W2007207512 modified "2023-10-18" @default.
• W2007207512 title "Gas-phase thermochemical properties of the bicarbonate and bisulfite ions" @default.
• W2007207512 cites W122375340 @default.
• W2007207512 cites W1543529383 @default.
• W2007207512 cites W1584871709 @default.
• W2007207512 cites W1963691784 @default.
• W2007207512 cites W1966101472 @default.
• W2007207512 cites W1967411905 @default.
• W2007207512 cites W1968384755 @default.
• W2007207512 cites W1970444746 @default.
• W2007207512 cites W1975224161 @default.
• W2007207512 cites W1978578205 @default.
• W2007207512 cites W1979004561 @default.
• W2007207512 cites W1981492958 @default.
• W2007207512 cites W1982069647 @default.
• W2007207512 cites W1985822262 @default.
• W2007207512 cites W1985825519 @default.
• W2007207512 cites W1987788488 @default.
• W2007207512 cites W1992791287 @default.
• W2007207512 cites W1995246260 @default.
• W2007207512 cites W1998575940 @default.
• W2007207512 cites W2000458277 @default.
• W2007207512 cites W2000918285 @default.
• W2007207512 cites W2013156028 @default.
• W2007207512 cites W2013711272 @default.
• W2007207512 cites W2016819489 @default.
• W2007207512 cites W2018094803 @default.
• W2007207512 cites W2018770868 @default.
• W2007207512 cites W2021324175 @default.
• W2007207512 cites W2023162752 @default.
• W2007207512 cites W2024914152 @default.
• W2007207512 cites W2026102507 @default.
• W2007207512 cites W2027981295 @default.
• W2007207512 cites W2028183663 @default.
• W2007207512 cites W2029957897 @default.
• W2007207512 cites W2032466705 @default.
• W2007207512 cites W2032916839 @default.
• W2007207512 cites W2035000885 @default.
• W2007207512 cites W2037682587 @default.
• W2007207512 cites W2040813419 @default.
• W2007207512 cites W2041216560 @default.
• W2007207512 cites W2042031376 @default.
• W2007207512 cites W2043800203 @default.
• W2007207512 cites W2046630856 @default.
• W2007207512 cites W2048318774 @default.
• W2007207512 cites W2048613175 @default.
• W2007207512 cites W2052978313 @default.
• W2007207512 cites W2055689696 @default.
• W2007207512 cites W2056052090 @default.
• W2007207512 cites W2058541740 @default.
• W2007207512 cites W2062125069 @default.
• W2007207512 cites W2064889778 @default.
• W2007207512 cites W2065566536 @default.
• W2007207512 cites W2070978027 @default.
• W2007207512 cites W2072686535 @default.
• W2007207512 cites W2074443653 @default.
• W2007207512 cites W2078232804 @default.
• W2007207512 cites W2078843151 @default.
• W2007207512 cites W2079487294 @default.
• W2007207512 cites W2080695842 @default.
• W2007207512 cites W2083616555 @default.
• W2007207512 cites W2086572863 @default.
• W2007207512 cites W2088051244 @default.
• W2007207512 cites W2089116038 @default.
• W2007207512 cites W2089262008 @default.
• W2007207512 cites W2089275658 @default.
• W2007207512 cites W2089943965 @default.
• W2007207512 cites W2090470824 @default.
• W2007207512 cites W2128711626 @default.
• W2007207512 cites W2158435561 @default.
• W2007207512 cites W2243823758 @default.
• W2007207512 cites W2281732907 @default.
• W2007207512 cites W2286313163 @default.
• W2007207512 cites W2306129169 @default.
• W2007207512 cites W2949506940 @default.
• W2007207512 cites W2949747290 @default.
• W2007207512 cites W2949821766 @default.
• W2007207512 cites W2950181872 @default.
• W2007207512 cites W2953195933 @default.
• W2007207512 cites W2953289153 @default.
• W2007207512 cites W2953365315 @default.
• W2007207512 cites W2954459995 @default.
• W2007207512 cites W3005034699 @default.
• W2007207512 cites W3043331741 @default.
• W2007207512 cites W4243331376 @default.
• W2007207512 cites W66195362 @default.
• W2007207512 doi "https://doi.org/10.1016/0168-1176(92)80114-g" @default.
• W2007207512 hasPublicationYear "1992" @default.
• W2007207512 type Work @default.
• W2007207512 sameAs 2007207512 @default.
• W2007207512 citedByCount "42" @default.
• W2007207512 countsByYear W20072075122012 @default.
• W2007207512 countsByYear W20072075122013 @default.
• W2007207512 countsByYear W20072075122014 @default.

• next