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- W2007210326 abstract "Abstract Indications are that CsPF 6 (I) at ambient conditions is cubic with a possible space group of Fm 3 m -O 5 h . A slight distortion of the unit cell cannot, however, be ruled out. Assuming Fm 3 m symmetry the Raman spectra of CsPF 6 (I) are consistent with a disordered model in which the PF − 6 ions are tilted away from the crystallographic axes. The phase transition which occurs below 90 K in CsPF 6 is reflected in the vibrational spectra and further significant changes occur below 60 K particularly in the Raman bands. It is not yet clear whether these changes represent the establishment of long-range order or whether a further phase of CsPF 6 exists below 60 K. A possible structure for CsPF 6 at very low temperatures is discussed." @default.
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- W2007210326 date "1981-08-01" @default.
- W2007210326 modified "2023-09-23" @default.
- W2007210326 title "The vibrational spectra and crystallographic properties of CsPF6" @default.
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- W2007210326 doi "https://doi.org/10.1016/0022-4596(81)90308-x" @default.
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