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- W2007219219 abstract "The reactions of 2-chloro-4,6-dimethylpyrimidine and 4-chloro-2,6-dimethylpyrimidine with some branched-alkyl- and dialkyl-amines have been followed from 30� to 70� in the absence of solvent. At comparable temperatures, alkylamines with β- or γ-branching approximated in reactivity to n-alkylamines, whereas those with α-branching and the di-n-alkylamines had only about 5% of the above reactivity; t-butylamine with two a-branches had but 0.1% of the reactivity of n-butylamine. Optimum conditions of time and temperature, calculated from these measurements, have been used to prepare 16 new alkylaminopyrimidines in good yield." @default.
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- W2007219219 date "1965-01-01" @default.
- W2007219219 modified "2023-10-17" @default.
- W2007219219 title "Pyrimidine reactions. IX. The amination of chloropyrimidines with branched alkylamines and Di-n-alkylamines" @default.
- W2007219219 doi "https://doi.org/10.1071/ch9650741" @default.
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