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- W2007219487 abstract "The structure, transport, thermodynamic properties, x-ray absorption spectra (XAS), and electronic structure of a new barium titanate suboxide, Ba1+δTi13−δO12 (δ = 0.11), are reported. It is a paramagnetic poor metal with hole carriers dominating the transport. Fermi liquid behavior appears at low temperature. The oxidization state of Ti obtained by the XAS is consistent with the metallic Ti2+ state. Local density approximation band structure calculations reveal the material is near the Van Hove singularity. The pseudogap behavior in the Ti-d band and the strong hybridization between the Ti-d and O-p orbitals reflect the characteristics of the building blocks of the Ti13 semi-cluster and the TiO4 quasi-squares, respectively." @default.
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- W2007219487 date "2015-04-01" @default.
- W2007219487 modified "2023-10-15" @default.
- W2007219487 title "Physical properties and electronic structure of a new barium titanate suboxide Ba1+δTi13−δO12 (δ = 0.11)" @default.
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- W2007219487 doi "https://doi.org/10.1063/1.4916991" @default.
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