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• W2007224305 abstract "Relaxation rates of carbon-13 magnetization of the C9 carbon positions in two poly-n-octyl star-hydrocarbon oils, 9-n-octyl-n-heptadecane and 9,10-di-n-octyl-n-octadecane, and of deuterium magnetization in 9-n-octyl-n-heptadecane-9d 1 and 9,10-di-n-octyl-n-octadecane-9d 1 , labelled with deuterium at the same carbon position, have been measured over wide ranges of temperature and at two field strengths. In this paper simulation of the observed relaxation rates within the assumptions of the Lipari and Szabo picture of molecular rotational diffusion, and dipolar and quadrupolar relaxation mechanisms, determined molecular rotational diffusion constants, activation energies, and Lipari and Szabo order parameters and correlation times for internal molecular motion at the labelled positions. The appropriate quadrupolar coupling constants could also be determined from the measured data. The effect of the rate of internal molecular isomerization was discussed and it was shown that in general this had to be included in the theoretical picture in order to derive a consistent set of motional parameters that generated all observable relaxation rates of magnetization." @default.
• W2007224305 created "2016-06-24" @default.
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• W2007224305 date "1997-01-01" @default.
• W2007224305 modified "2023-09-25" @default.
• W2007224305 title "Deuterium and Carbon-13 NMR Study of Molecular Rotational Diffusion in Two Star-Hydrocarbon Oils" @default.
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• W2007224305 doi "https://doi.org/10.1002/bbpc.19971010113" @default.
• W2007224305 hasPublicationYear "1997" @default.
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