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- W2007241507 abstract "The dynamics of the H atom formation channel in the reaction of metastable oxygen atoms O(1D) with methane were studied in the gas phase using the pulsed laser photolysis/vacuum-UV laser-induced fluorescence “pump-and-probe” technique. Translationally energetic O(1D) atoms with an average collision energy of 37 kJ/mol in the O(1D)−CH4 center-of-mass system were generated by laser photolysis of N2O at 193 nm. Nascent H atoms produced in reactive collisions of O(1D) with room-temperature CH4 molecules were detected with sub-Doppler resolution via (2p2P ← 1s2S) laser-induced fluorescence. An absolute reaction cross section of σH(37 kJ/mol) = 1.4 ± 0.5 Å2 was determined for the H atom formation channel by means of a calibration method. From the H atom Doppler profiles measured under single-collision conditions the product translational energy release was determined." @default.
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- W2007241507 date "1998-05-13" @default.
- W2007241507 modified "2023-10-18" @default.
- W2007241507 title "Absolute Reactive Cross Section for H Atom Formation in the Reaction of Translationally Energetic O(<sup>1</sup>D) Atoms with Methane" @default.
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- W2007241507 doi "https://doi.org/10.1021/jp980652y" @default.
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