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- W2007277941 abstract "Achiral ferrocene diol, 1,1′-bis(diphenylhydroxymethyl)ferrocene 5, was prepared by the direct dilithiation of ferrocene with n-butyllithium in the presence of TMEDA followed by treatment with benzophenone, while the first chiral C2-symmetric ferrocene diol possessing only the planar chirality, (+)-(R,R)-1,1′-bis(diphenylhydroxymethyl)-2,2′-dimethylferrocene 6, was prepared from (+)-(R,R)-1,1′-bis(oxazolinyl)-2,2′-dimethylferrocene 1b by the transformation of the oxazoline moieties. It was shown that diols 5 and 6 can form 1:1 complexes with tetraisopropyl titanate with ease. The X-ray crystal structure analysis of 5 with an intramolecular hydrogen-bonding showed that the phenyl groups in the molecule occupy quasi-axial and quasi-equatorial positions and these structures can be taken as the models of the titanium complexes of ferrocene diols. As a preliminary experiment, the titanium-catalyzed hydrosilylation of a ketone with 6 has also been carried out." @default.
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- W2007277941 date "1999-02-01" @default.
- W2007277941 modified "2023-09-23" @default.
- W2007277941 title "Achiral and planar chiral ferrocene diols: preparation and complexation with titanium(IV)" @default.
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- W2007277941 doi "https://doi.org/10.1016/s0022-328x(98)00930-9" @default.
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