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- W2007279325 abstract "The mechanism of the rearrangement of 4-alkyltriazoles to the corresponding 1-alkyltriazoles on thermolysis at 330 °C is shown to involve initial formation of an intermediate 1,4-dialkyltriazolium triazolate salt. The triazolate ion subsequently attacks at the alkyl group bearing 1- and 4-positions of the dialkyltriazolium ion, yielding the observed products. No evidence for unimolecular reaction steps has been found. The triazole moiety in these compounds is only a weak leaving group, which requires activation by alkylation. Unimolecular reaction steps never take place, neither from neutral triazole species nor from activated dialkyl-substituted triazolium species." @default.
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- W2007279325 date "2000-11-01" @default.
- W2007279325 modified "2023-09-25" @default.
- W2007279325 title "Thermolysis of Triazoles as Melts − Is the 3,5-Diphenyl-1,2,4-triazole Group a Good Leaving Group?" @default.
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- W2007279325 doi "https://doi.org/10.1002/1099-0690(200011)2000:22<3749::aid-ejoc3749>3.0.co;2-x" @default.
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