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- W2007309025 abstract "The appearance of metastable apatite-like phases during the oxidation of Eu2SiO4 to Eu2SiO5 is discussed in terms of topotaxy. From dta and tga experiments, which are correlated with X-ray single crystal and powder data, the first step in the partial oxidation at 500°C is suggested to be due to the formation of Eu apatite. The silicate apatite crystals show a stoichiometry different from Eu2SiO4 and Eu2SiO5. However, they contain strings of [EuO9] polyhedra, which are very similar to the structure of high-Eu2SiO4. This favours the reaction towards Eu2+ and Eu3+ containing apatite I initially. Finally Eu2SiO5 is observed above 1000°C after the excess of EuO has been oxidized to Eu2O3 and partially incorporated to apatite II." @default.
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- W2007309025 date "1972-07-01" @default.
- W2007309025 modified "2023-09-26" @default.
- W2007309025 title "Thermal oxidation of Eu2SiO4—a topotactic solid state reaction" @default.
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- W2007309025 doi "https://doi.org/10.1016/0022-4596(72)90008-4" @default.
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