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- W2007332006 endingPage "10978" @default.
- W2007332006 startingPage "10972" @default.
- W2007332006 abstract "Abstract The carbene or carbocationic nature of the intermediates in the gold‐catalyzed cycloisomerization of 1,5‐enynes can be revealed, depending on the ligands on the gold catalysts. Gold complexes with highly electron‐donating ligands promote reactions that proceed via intermediates with carbene‐like character, leading to products with a bicyclo[3.1.0]hexene skeleton. The intermediate cyclopropyl endo ‐gold carbenes formed in this cyclization have been trapped, for the first time, to give biscyclopropane derivatives in a reaction that proceeds in a concerted fashion, according to DFT calculations." @default.
- W2007332006 created "2016-06-24" @default.
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- W2007332006 date "2011-08-17" @default.
- W2007332006 modified "2023-10-18" @default.
- W2007332006 title "Nature of the Intermediates in Gold(I)-Catalyzed Cyclizations of 1,5-Enynes" @default.
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- W2007332006 doi "https://doi.org/10.1002/chem.201101749" @default.
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