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- W2007332094 abstract "The reduction of HTeO2+ in the presence of various inorganic salts and ions has been studied at rotating glassy carbon and dropping mercury electrodes. The effect of added sodium salts (NaSO4, NaCl, NaNO3) was attributed to the anion present. SO42− ions caused both a negative shift in the deposition potential and a decrease in the limiting current without changing the deposit morphology. Cl− ions caused a positive shift in the deposition potential, but no change in the limiting current, while NO3− had no effect n either current or potential. Neither Cl− nor NO3− caused changes in deposit morphology. The effect of SO42− is xplained by complex or ion-pair formation between HTeO2+ and SO42−. Addition of a wide concentration range of CdSO4 caused a decrease in the limiting current similar to that produced by SO42− alone, but with no change in deposition potential. A dramatic change in deposit morphology from dendritic to smooth, due to CdTe formation, also accompanied CdSO4 addition. However, deposit analysis revealed that conversion of Te to CdTe was incomplete at 298 K, even with a very large excess of Cd2+ over HTeO2+." @default.
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- W2007332094 date "1992-07-01" @default.
- W2007332094 modified "2023-10-18" @default.
- W2007332094 title "An investigation into the effect of ionic species on the deposition of tellurium and the formation of cadmium telluride" @default.
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- W2007332094 doi "https://doi.org/10.1016/0022-0728(92)80397-m" @default.
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