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- W2007335339 abstract "Photoelectron spectroscopic measurements of core-electron levels in cations of transition-series insulators commonly show ``satellite'' features in the vicinity of the ``main'' photoelectron peaks. In this paper, the relationship between main lines and adjacent satellites is systematically examined for 3d-series insulators. The spectral features are interpreted using a relaxation model that allows for the possibility of different final-state screening conditions of the photoinduced hole. Systematic trends are examined by employing atomic calculations and utilizing transition-state theory to calculate electron removal energies for atoms in appropriately simulated chemical environments. It is demonstrated that the main-line and satellite energies are both dependent on the cation charge environment but with different degrees of sensitivity. The consequence is that sensitivity to chemical change can be monitored in the observed main-line to satellite separation. Model predictions are tested by monitoring the dependence of the satellite separations on the cation valence state and on the electronegativity of both cations and ligated anions. Systematic tests are applied to 3d-series insulators but more general applicability of the relaxation model is also discussed." @default.
- W2007335339 created "2016-06-24" @default.
- W2007335339 creator A5003746725 @default.
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- W2007335339 date "1985-04-15" @default.
- W2007335339 modified "2023-09-27" @default.
- W2007335339 title "Final-state screening and chemical shifts in photoelectron spectroscopy" @default.
- W2007335339 cites W1649897654 @default.
- W2007335339 cites W1964220875 @default.
- W2007335339 cites W1965445375 @default.
- W2007335339 cites W1966016366 @default.
- W2007335339 cites W1966909279 @default.
- W2007335339 cites W1971409724 @default.
- W2007335339 cites W1972100113 @default.
- W2007335339 cites W1980051622 @default.
- W2007335339 cites W1981425145 @default.
- W2007335339 cites W1987660920 @default.
- W2007335339 cites W1988971768 @default.
- W2007335339 cites W1989779800 @default.
- W2007335339 cites W1993174962 @default.
- W2007335339 cites W1995896456 @default.
- W2007335339 cites W1997341362 @default.
- W2007335339 cites W2003661696 @default.
- W2007335339 cites W2008107956 @default.
- W2007335339 cites W2008939865 @default.
- W2007335339 cites W2009791808 @default.
- W2007335339 cites W2012704273 @default.
- W2007335339 cites W2016367977 @default.
- W2007335339 cites W2016596574 @default.
- W2007335339 cites W2017551762 @default.
- W2007335339 cites W2017986700 @default.
- W2007335339 cites W2022707427 @default.
- W2007335339 cites W2024500233 @default.
- W2007335339 cites W2025252604 @default.
- W2007335339 cites W2026704985 @default.
- W2007335339 cites W2032570056 @default.
- W2007335339 cites W2034019090 @default.
- W2007335339 cites W2034419941 @default.
- W2007335339 cites W2035193824 @default.
- W2007335339 cites W2035607784 @default.
- W2007335339 cites W2036406479 @default.
- W2007335339 cites W2036807292 @default.
- W2007335339 cites W2038587897 @default.
- W2007335339 cites W2043563170 @default.
- W2007335339 cites W2050330355 @default.
- W2007335339 cites W2052835130 @default.
- W2007335339 cites W2053664439 @default.
- W2007335339 cites W2060891165 @default.
- W2007335339 cites W2061130945 @default.
- W2007335339 cites W2063954992 @default.
- W2007335339 cites W2064421901 @default.
- W2007335339 cites W2064594652 @default.
- W2007335339 cites W2065283508 @default.
- W2007335339 cites W2067063383 @default.
- W2007335339 cites W2067138899 @default.
- W2007335339 cites W2067963503 @default.
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- W2007335339 cites W2070507078 @default.
- W2007335339 cites W2071039330 @default.
- W2007335339 cites W2074567933 @default.
- W2007335339 cites W2075634268 @default.
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- W2007335339 cites W2080655459 @default.
- W2007335339 cites W2082188780 @default.
- W2007335339 cites W2083904071 @default.
- W2007335339 cites W2085047049 @default.
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- W2007335339 cites W2092702062 @default.
- W2007335339 cites W2092926523 @default.
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- W2007335339 cites W2167590372 @default.
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- W2007335339 cites W636232760 @default.
- W2007335339 cites W64231267 @default.
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- W2007335339 doi "https://doi.org/10.1103/physrevb.31.5399" @default.
- W2007335339 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/9936507" @default.
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