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- W2007338701 abstract "The reaction of the amino(aryl)diphosphene, ArylNH-P=P-Aryl (Aryl=2,4,6- t Bu 3 C 6 H 2 ) 1 with PCl 5 leads to the amino-1,2-dihalogeno(aryl)diphosphine, ArylNH-P(Cl)-P(Cl)-Aryl 2 , which is transformed into the P-Chloro-azadiphosphiridine, Cl-P-N(Aryl)-P-Aryl 3 , via base-induced hydrogen elimination. Nucleophilic displacement of the halide in 3 by lithium alkyls gives the corresponding substitution products, R-P-N(Aryl)-P-Aryl (R= Me ( 4a ), n Bu ( 4b ), and t Bu ( 4c ) respectively), which rearrange thermally into the diphosphene-imines, R-P(=NAryl)=PAryl 5a–c . Cl/H-exchange in 3 with n Bu 3 SnH leads to the formation of the aminodiphosphene 1 . The structure of 5c (R= t Bu) has been elucidated by a X-ray study." @default.
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- W2007338701 date "1993-09-01" @default.
- W2007338701 modified "2023-10-17" @default.
- W2007338701 title "Ringöffnungsreaktionen von azadiphosphiridinen" @default.
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- W2007338701 doi "https://doi.org/10.1016/s0040-4039(00)60641-x" @default.
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