Matches in SemOpenAlex for { <https://semopenalex.org/work/W2007339711> ?p ?o ?g. }
Showing items 1 to 86 of
86
with 100 items per page.
- W2007339711 endingPage "1654" @default.
- W2007339711 startingPage "1649" @default.
- W2007339711 abstract "The stereospecific synthesis of the three isomers of 3,7-dimethylbicyclo[3.3.1]nonane is described. The conformations of these compounds were studied with the use of 13C and 1H NMR spectroscopy. The 3β,7β-dimethyl derivative exists predominantly in the cc conformation, the 3α,7β-dimethyl derivative predominantly in the bc conformation, whereas 3α,7β-dimethylbicyclo[3.3.1]nonane exists as a mixture of the cbbc and the t-bb conformations, which rapidly interconvert. The ΔH and ΔS values for the conformational equilibrium in question, were determined by variable temperature13C NMR. The results of these experiments fit well with those of molecular mechanics. The enthalpies of activation of the interconversion of the various conformers of 3α,7α-dimethylbicyclo[3.3.1]nonane were also calculated and compared with those of the parent system bicyclo[3.3.1]nonane." @default.
- W2007339711 created "2016-06-24" @default.
- W2007339711 creator A5011625458 @default.
- W2007339711 creator A5048387569 @default.
- W2007339711 creator A5053565347 @default.
- W2007339711 creator A5057574305 @default.
- W2007339711 creator A5064142099 @default.
- W2007339711 creator A5064637426 @default.
- W2007339711 date "1983-01-01" @default.
- W2007339711 modified "2023-10-16" @default.
- W2007339711 title "Synthesis and conformational analysis of the three 3,7-dimethylbicyclo[3.3.1]nonanes" @default.
- W2007339711 cites W1508378683 @default.
- W2007339711 cites W1558260213 @default.
- W2007339711 cites W1842350169 @default.
- W2007339711 cites W1966791420 @default.
- W2007339711 cites W2014736376 @default.
- W2007339711 cites W2042621788 @default.
- W2007339711 cites W2042774889 @default.
- W2007339711 cites W2048498349 @default.
- W2007339711 cites W2052608104 @default.
- W2007339711 cites W2058629965 @default.
- W2007339711 cites W2064531650 @default.
- W2007339711 cites W2087812455 @default.
- W2007339711 cites W2937800770 @default.
- W2007339711 cites W53123824 @default.
- W2007339711 doi "https://doi.org/10.1016/s0040-4020(01)88576-8" @default.
- W2007339711 hasPublicationYear "1983" @default.
- W2007339711 type Work @default.
- W2007339711 sameAs 2007339711 @default.
- W2007339711 citedByCount "15" @default.
- W2007339711 crossrefType "journal-article" @default.
- W2007339711 hasAuthorship W2007339711A5011625458 @default.
- W2007339711 hasAuthorship W2007339711A5048387569 @default.
- W2007339711 hasAuthorship W2007339711A5053565347 @default.
- W2007339711 hasAuthorship W2007339711A5057574305 @default.
- W2007339711 hasAuthorship W2007339711A5064142099 @default.
- W2007339711 hasAuthorship W2007339711A5064637426 @default.
- W2007339711 hasConcept C106159729 @default.
- W2007339711 hasConcept C111771559 @default.
- W2007339711 hasConcept C147597530 @default.
- W2007339711 hasConcept C161790260 @default.
- W2007339711 hasConcept C162324750 @default.
- W2007339711 hasConcept C178790620 @default.
- W2007339711 hasConcept C185592680 @default.
- W2007339711 hasConcept C18705241 @default.
- W2007339711 hasConcept C187921627 @default.
- W2007339711 hasConcept C24961977 @default.
- W2007339711 hasConcept C2778265757 @default.
- W2007339711 hasConcept C32909587 @default.
- W2007339711 hasConcept C66974803 @default.
- W2007339711 hasConcept C71240020 @default.
- W2007339711 hasConceptScore W2007339711C106159729 @default.
- W2007339711 hasConceptScore W2007339711C111771559 @default.
- W2007339711 hasConceptScore W2007339711C147597530 @default.
- W2007339711 hasConceptScore W2007339711C161790260 @default.
- W2007339711 hasConceptScore W2007339711C162324750 @default.
- W2007339711 hasConceptScore W2007339711C178790620 @default.
- W2007339711 hasConceptScore W2007339711C185592680 @default.
- W2007339711 hasConceptScore W2007339711C18705241 @default.
- W2007339711 hasConceptScore W2007339711C187921627 @default.
- W2007339711 hasConceptScore W2007339711C24961977 @default.
- W2007339711 hasConceptScore W2007339711C2778265757 @default.
- W2007339711 hasConceptScore W2007339711C32909587 @default.
- W2007339711 hasConceptScore W2007339711C66974803 @default.
- W2007339711 hasConceptScore W2007339711C71240020 @default.
- W2007339711 hasIssue "9" @default.
- W2007339711 hasLocation W20073397111 @default.
- W2007339711 hasOpenAccess W2007339711 @default.
- W2007339711 hasPrimaryLocation W20073397111 @default.
- W2007339711 hasRelatedWork W1966083136 @default.
- W2007339711 hasRelatedWork W1983839742 @default.
- W2007339711 hasRelatedWork W1988033651 @default.
- W2007339711 hasRelatedWork W1998242196 @default.
- W2007339711 hasRelatedWork W2007339711 @default.
- W2007339711 hasRelatedWork W2022766953 @default.
- W2007339711 hasRelatedWork W2046486814 @default.
- W2007339711 hasRelatedWork W2076770037 @default.
- W2007339711 hasRelatedWork W2079543419 @default.
- W2007339711 hasRelatedWork W3211165588 @default.
- W2007339711 hasVolume "39" @default.
- W2007339711 isParatext "false" @default.
- W2007339711 isRetracted "false" @default.
- W2007339711 magId "2007339711" @default.
- W2007339711 workType "article" @default.