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• W2007341320 endingPage "1445" @default.
• W2007341320 startingPage "1431" @default.
• W2007341320 abstract "The reaction between the NiA(ClO4)2 and NaHL2 {where A = 14ane[N4], the macrocyclic ligands derived from the product of template condensation of 2,6-diacetylpyridine with aliphatic 3,3′-diaminodipropylamine, NH2(CH2)3NH(CH2)3NH2; and L = 2-cyano-2-isonitrosoacetamide anion, ACO− (amidecyanoxime, NC-C(NO)-C(O) )} has led to the formation of a highly unusual trimetallic bis-[ fac-(triscyanoximato) nickel(II)] anionic complex anion instead of the expected Ni(II) macrocyclic complex with coordinated cyanoxime ligands. Two equivalent and symmetric trigonal-prismatic NiL units are connected to form the [NaNi2L6]− anion by the presence of a central sodium cation. The latter is located between two NiL anions and has an octahedral NaO6 geometry comprised of oxygen atoms of the nitroso group of the cyanoxime ligand. The oxime ligand is planar and adopts a cis-anti configuration in the complex." @default.
• W2007341320 created "2016-06-24" @default.
• W2007341320 creator A5077833177 @default.
• W2007341320 creator A5078752885 @default.
• W2007341320 date "2004-11-11" @default.
• W2007341320 modified "2023-09-27" @default.
• W2007341320 title "Demetallation of a Ni(II) tetraazamacrocyclic complex by cyanoxime resulting in the formation of a stereospecific trinuclear compound [Na(H₂O)₆]⁺[NaNi₂L₆]⁻ (L = NC-C(NO)-C(O)NH )" @default.
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• W2007341320 doi "https://doi.org/10.1080/00958970412331312652" @default.
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