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- W2007342816 abstract "Environmental Context.Effective management of eutrophication and resultant major algal blooms requires accurate assessment of the importance of internal (sediment-based) as well as external, sources of phosphorus to susceptible aquatic ecosystems. The high spatial variability in pore water filterable reactive phosphorus (FRP) necessitates extensive sampling, and rapid flow injection methods overcome many of the difficulties in maintaining sample integrity. A simple flow injection manifold has been developed to prevent major sulfide interference with FRP determination and therefore enable accurate phosphate measurements. Abstract.Simple on-line sulfide removal using potassium permanganate (KMnO4) was incorporated into a spectrophotometric flow injection (FI) system for phosphate determination using molybdenum blue with ascorbic acid as the reductant. Excess KMnO4 was reduced before the sample zone passed through the detector and the method effectively removed all sulfide interference. Without this removal, sulfide interference caused major errors in filterable reactive phosphorus (FRP) analyses. Some model organic phosphates were tested with the permanganate manifold and there was no conversion to phosphate. With the KMnO4 carrier, the calibration plot was linear over the tested range (0–1000 μg L−1 P), with a detection limit of 38 μg L−1 P. Precision was typically better than 2.5%, based on triplicate injections. FRP determinations on anoxic, estuarine pore water samples were in excellent agreement with the conventional batch method with prior acidification and sparging, but avoided sample pretreatment and the generation of toxic H2S. Samples spiked with phosphate gave recoveries of 93–104%. Given the simplicity of modifying conventional FI manifolds to incorporate the improvements described here, it is recommended that all FRP measurements by FI replace water as the carrier with 0.01 M KMnO4 whenever the presence of sulfide is suspected." @default.
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- W2007342816 date "2006-01-01" @default.
- W2007342816 modified "2023-09-23" @default.
- W2007342816 title "On-line Removal of Sulfide Interference in Phosphate Determination by Flow Injection Analysis" @default.
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- W2007342816 doi "https://doi.org/10.1071/en05086" @default.
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