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- W2007348728 abstract "A cationic rhodium(I) complex, viz. Rh NBD diphos+ 4-CH3-C6H5SO3− [NBD = norbornadiene, diphos = (C6H5)2 P-CH2-CH2-P(C6H5)2], has been used as a homogeneous catalyst for the hydrogenation of soybean oil in acetone solution. This complex acts almost in the same way as the corresponding ones with ClO4− or PF6− as conuterions, i.e., it gives high polyene selectivity and low formation oftrans isomers. Because of the somewhat stronger basic character of the p-toluene-sulfonate ion compared with the perchlorate and hexafluorphosphate ions, the relative proportion of reaction via the so-called monohydride path is larger in the present case. When the ionic complex, Rh NBD diphos+, is bound to a solid support, e.g., to the anionic sites of sulfonated polystyrene resins, a nearly total lack of catalytic activity is observed. Possible reasons for these effects are discussed-in terms of π-arene-metal binding and covalent coordination of the sulfonate group." @default.
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- W2007348728 date "1984-08-01" @default.
- W2007348728 modified "2023-09-27" @default.
- W2007348728 title "Hydrogenation of soybean oil with cationic Rh(I)-Phosphine complexes as catalysts - Para-toluene sulfonate and sulfonated styrene resins as counterions" @default.
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- W2007348728 doi "https://doi.org/10.1007/bf02542240" @default.
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