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- W2007352836 abstract "An examination of the crystal structure of the title complex revealed three pathways for magnetic exchange. Analysis of the bulk magnetic susceptibility data in the temperature range 5--303 K gave a value of J=-1.25 ${mathrm{cm}}^{mathrm{ensuremath{-}}1}$ for the intradimer coupling. Single-crystal EPR spectra showed anomalous angular variation from which the molecular ssg tensor was derived using a decoupling procedure. The two intermolecular couplings [ensuremath{Vert}J'ensuremath{Vert}=0.0006(2) ${mathrm{cm}}^{mathrm{ensuremath{-}}1}$ at 300 K and 0.0001(2) ${mathrm{cm}}^{mathrm{ensuremath{-}}1}$ at 147 K, and J''ensuremath{ge}0.056 ${mathrm{cm}}^{mathrm{ensuremath{-}}1}$] involving multiatomic bridges were also derived from the EPR data. J'' involves equatorial-equatorial exchange between two coupled centers separated by 11.75 AA{} and is stronger than the axial-equatorial exchange between centers separated by 7.73 AA{}. The results were analyzed on the basis of a model that assumes participation of the uncoordinated lattice water in propagating exchange interaction through H bonds. Interpretation of the molecular ssg tensor resulted in an ensuremath{Vert}${mathit{x}}^{2}$-${mathit{y}}^{2}$〉 ground state with very little mixing of ensuremath{Vert}3${mathit{z}}^{2}$-${mathit{r}}^{2}$〉. The negligible electron density in the axial direction is responsible for the weak J'." @default.
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- W2007352836 date "1990-11-01" @default.
- W2007352836 modified "2023-09-27" @default.
- W2007352836 title "Long-range exchange interaction in (2,2’-bipyridine-3,3’-dicarboxylic acid)dichlorocopper(II) monohydrate via lattice water: Single-crystal EPR studies" @default.
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- W2007352836 doi "https://doi.org/10.1103/physrevb.42.7794" @default.
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